Search citation statements
Paper Sections
Citation Types
Year Published
Publication Types
Relationship
Authors
Journals
The development of highly efficient sensors for lowconcentration SO 2 at room temperature is important for human health and fine chemistry, but it still faces critical challenges. Herein, a scalable olefin-linked covalent organic framework (COF) with an ultramicroporous structure and abundant binding sites is first developed as the SO 2 sensing material. The COF can adsorb SO 2 of 220 cm 3 /g at 1 bar and 40 cm 3 /g at 0.01 bar and 298 K, surpassing all reported COFs. The computational and kinetic adsorption studies deeply unveil the selective adsorption mechanism for low-concentration SO 2 . Furthermore, the multicomponent gas mixture breakthrough experiments confirm that the COF can specifically capture low-concentration (2000 ppm) SO 2 . We innovated a melt polymerization technology to fabricate COF films with adjustable substrates and film thicknesses. COF films are directly grown on the interdigital electrodes to prepare the SO 2 sensor device, which possesses a low detection limit (86 ppb) and excellent selectivity for SO 2 in the presence of 10 other potentially interfering gases. Compared to other reported SO 2 sensors, its overall performance is among the top. Prominently, the sensor maintains a stable output signal for more than two months, and recovery can be easily achieved by simply purifying nitrogen at room temperature without heating. This study marks the first use of COFs for SO 2 sensing, opening new possibilities for COFs in the detection of low-concentration toxic gases and manufacturing gas sensor devices.
The development of highly efficient sensors for lowconcentration SO 2 at room temperature is important for human health and fine chemistry, but it still faces critical challenges. Herein, a scalable olefin-linked covalent organic framework (COF) with an ultramicroporous structure and abundant binding sites is first developed as the SO 2 sensing material. The COF can adsorb SO 2 of 220 cm 3 /g at 1 bar and 40 cm 3 /g at 0.01 bar and 298 K, surpassing all reported COFs. The computational and kinetic adsorption studies deeply unveil the selective adsorption mechanism for low-concentration SO 2 . Furthermore, the multicomponent gas mixture breakthrough experiments confirm that the COF can specifically capture low-concentration (2000 ppm) SO 2 . We innovated a melt polymerization technology to fabricate COF films with adjustable substrates and film thicknesses. COF films are directly grown on the interdigital electrodes to prepare the SO 2 sensor device, which possesses a low detection limit (86 ppb) and excellent selectivity for SO 2 in the presence of 10 other potentially interfering gases. Compared to other reported SO 2 sensors, its overall performance is among the top. Prominently, the sensor maintains a stable output signal for more than two months, and recovery can be easily achieved by simply purifying nitrogen at room temperature without heating. This study marks the first use of COFs for SO 2 sensing, opening new possibilities for COFs in the detection of low-concentration toxic gases and manufacturing gas sensor devices.
Gas sensors are essential for safety and quality of life, with broad applications in industry, healthcare, and environmental monitoring. As urbanization and industrial activities intensify, the need for advanced air quality monitoring becomes critical, driving the demand for more sensitive, selective, and reliable sensors. Recent advances in nanotechnology, particularly 1D nanostructures like nanofibers and nanowires, have garnered significant interest due to their high surface area and improved charge transfer properties. Electrospinning stands out as a promising technique for fabricating these nanomaterials, enabling precise control over their morphology and leading to sensors with exceptional attributes, including high sensitivity, rapid response, and excellent stability in harsh conditions. This review examines the current research on chemoresistive gas sensors based on 1D nanostructures produced by electrospinning. It focuses on how the morphology and composition of these nanomaterials influence key sensor characteristics—sensitivity, selectivity, and stability. The review highlights recent advancements in sensors incorporating metal oxides, carbon nanomaterials, and conducting polymers, along with their modifications to enhance performance. It also explores the use of fiber-based composite materials for detecting oxidizing, reducing, and volatile organic compounds. These composites leverage the properties of various materials to achieve high sensitivity and selectivity, allowing for the detection of a wide range of gases in diverse conditions. The review further addresses challenges in scaling up production and suggests future research directions to overcome technological limitations and improve sensor performance for both industrial and domestic air quality monitoring applications.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
customersupport@researchsolutions.com
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Copyright © 2024 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.