Ultrasonic atomization technology has been widely used in industry in recent years due to its higher atomization e ciency. This paper proposes a method of electrostatic-assisted ultrasonic atomization spraying and designs a special ultrasonic power supply that can directly introduce high-voltage static electricity onto the surface of the ultrasonic atomization so that the liquid can contact the charge and enhance the charging effect. This paper conducts numerical simulation analysis on the atomization process and statistically analyzes the numerical simulation atomization particle size through image processing. In addition, this paper designs experiments from two aspects of atomization particle size and lm-forming effect. The results show that the experimental results are consistent with the numerical simulation results, verifying the accuracy of the numerical simulation results. It shows that in the process of sub-droplet formation, the introduction of static electricity will increase the number of capillary waves, promote two mechanisms of the capillary pinch-off mechanism and the Rayleigh-Plain instability, reduce atomization particle size, and increase atomization e ciency. Compared with the traditional air ow beam method, the lm-forming surface quality of the electric eld beam method is higher and the surface roughness is lower. It solves the problem that air ow affects lm-forming quality in traditional ultrasonic spraying with the air ow beam method. It provides a theoretical basis and scienti c guidance for the application of electrostatic-assisted ultrasonic atomization technology in the atomization and lm preparation industry.