Electrosynthesis of iron-based metal-organic materials with bis(salicylic acid) derivatives

Abstract

Continuous advancements in understanding and controlling surface functionalisation and properties empower materials scientists to design materials with tailored characteristics, improved performance, and enhanced functionality, thereby expanding scientific knowledge and technological progress. This research paper presents the synthesis of two new metal-organic material-based films using the cathodic electrodeposition method. In contrast with the anodic deposition method, the cathodic deposition method offers the advantage of using non-metal electrode substrates and various metal ions, a unique aspect not yet fully explored. The study investigates the effects of linker length using 2,5-dihydroxyterephthalic acid (DOBDC) and 3,3'-dihydroxybiphenyl-4,4'-dicarboxylic acid (BPP) as organic linkers and iron(III) as the metal node for the structures. The films' electrochemical behaviour, characterisation through techniques like infrared spectroscopy, scanning electron microscopy, X-ray photoelectron spectroscopy, X-Ray powder diffraction and grazing-Incidence small-angle X-ray scattering and particle-induced X-ray emission, as well as results from cyclic voltammetry studies, are discussed. The films were found to be nearly amorphous with specific grain sizes, revealing heterogeneity in composition and thickness. The unique synthesis method and comprehensive characterisation offer insights into the potential of electrosynthesis for designing functional materials and encourage further exploration of various synthesis conditions and metal ions.