1961
DOI: 10.1016/0013-4686(61)80001-7
|View full text |Cite
|
Sign up to set email alerts
|

Elektrochemisches verhalten anodisch hergestellter oxidschichten auf platin

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
1
1
1

Citation Types

0
7
0

Year Published

1962
1962
1986
1986

Publication Types

Select...
5
2

Relationship

0
7

Authors

Journals

citations
Cited by 22 publications
(7 citation statements)
references
References 16 publications
0
7
0
Order By: Relevance
“…Films corresponding to about 10 mC/cm 2 have been reported on Pt anodized in M KOH, in a somewhat obscurely presented Russian paper (36). Other voltammetric studies where phase oxides were certainly involved include those of Fleischmann et al (5) and Nagel and Dietz (22).…”
Section: Resultsmentioning
confidence: 96%
See 3 more Smart Citations
“…Films corresponding to about 10 mC/cm 2 have been reported on Pt anodized in M KOH, in a somewhat obscurely presented Russian paper (36). Other voltammetric studies where phase oxides were certainly involved include those of Fleischmann et al (5) and Nagel and Dietz (22).…”
Section: Resultsmentioning
confidence: 96%
“…After k9, the much milder treatment of o8, where the potential was between 2.20 and 2.15V for only 5 rain, gave a sharp second peak in the cathodic voltammogram with Q2 = 2.4 mC/cmL Apart from the great hysteresis in oxidizability evident in Table Ia, it is obvious that the magnitude of the anode potential, provided it exceeds a certain minimum value of about 2.15V, RHE, has a relatively minor influence on second oxide formation. A hysteresis in the anodic oxidizability of Pt was briefly alluded to by Nagel and Dietz (22). They noted that during a sequence of electrolytic oxidations and reductions the anodizing time required to form a brown layer of phase oxide fell from 15 hr to 1 hr and ascribed this behavior to a gradual loosening ("Auflockerung") of the metal surface.…”
Section: Hysteresis In Oxidizability (Second Oxide)mentioning
confidence: 99%
See 2 more Smart Citations
“…E1 Wakkad (20) reports that the potential of a Pt/PtO couple is about 0.88v in acid solution. Since this oxide layer is an electronic conductor (22), additional layers can be formed only under extreme conditions (25). However, Latimer (11) and others (24) report a value of 0.98v for a Pt/Pt(OH)~ couple in acid solution which is based on thermochemical data obtained from a chemically prepared compound.…”
Section: The Platinum-platinum Oxide Couples--anothermentioning
confidence: 99%