“…Since the theoretical prediction of the first half-metallic material, 1 the half-Heusler alloy NiMnSb, many other Heusler alloy systems have been predicted to be half-metallic including Co 2 MnGe and Co 2 MnSi, and much experimental work followed. [2][3][4][5][6][7][8] It was found that many of the physical properties of these systems, including the degree of spin polarization, are diminished by physical occurrences in the system, the most common ones being forms of disorder including, primarily, antisite disorder, which has been observed experimentally. 9,10 For instance, it was predicted that Co antisite disorder in Co 2 MnSi introduced a finite contribution in the gap of the minority density of states, resulting in suboptimum spin polarization, i.e., far below the predicted values.…”