Rydberg atom electric field sensors are projected to enable novel capabilities for resilient communications and sensing. This quantum sensor is small-size, highly sensitive, and broadly tunable, and it has the potential for performing precision vector electric field and angle-of-arrival measurements. While these atomic electric field sensors will not replace traditional receivers in commodity applications for RF signal reception, these sensors could be an enabling technology in niche application spaces. This review outlines the principles of operation of atomic electric field sensors and compares their performance capabilities to traditional RF receivers. It also highlights recent research and development efforts in atomic electric field sensing and identifies applications for which these sensors are projected to impact communications and remote sensing.