Emerging molecular design strategies of unsymmetrical phthalocyanines for dye-sensitized solar cell applications

Abstract

In recent years, dye-sensitized solar cells (DSSCs) have emerged as one of the possible solutions for the global energy crisis. Among the various components of DSSCs, the sensitizer, which harvests solar energy and injects electrons in to the semiconductor layer, plays a crucial role in achieving high efficiency and durability of the cell. To date ruthenium(II) sensitizers exhibit high efficiencies (>11.5%), but they are not so suitable for roof-top/commercial applications mainly because of their limited harvesting capability, expensive ruthenium metal and low durability. In this context, various sensitizers which include porphyrins, phthalocyanines and metal-free organic dye sensitizers have been developed and some of them were found to exhibit enhanced efficiencies compared to classical ruthenium(II) sensitizers. Man-made tetrapyrrolic systems, phthalocyanines (Pcs) have also been studied significantly because of their unique thermal and electronic properties in the red and near-IR regions. Over the years, the efficiency of Pc-based DSSC has improved to 6.1% by synthesizing various Pc derivatives and optimizing fabrication parameters. However, in the present review article, only the recent developments in Pc-based DSSCs have been documented in detail. This review also emphasizes different molecular engineering approaches that the researchers developed for achieving higher efficiency.

Triphenylamine-functionalized corrole sensitizers for solar-cell applications

“…However, ruthenium complexes are exclusive due to rarity, tedious purification methods and lack of absorption in the near‐IR region of the solar spectrum. For this reason intensive investigations have been carried out into alternative sensitizers such as metal‐free organic dyes and closed ring structures like porphyrins and phthalocyanines . Significantly, a porphyrin dye has recently shown photovoltaic conversion efficiencies exceeding 13%, in combination with a Co (II)/Co (III) redox electrolyte .…”

Enhanced Charge Separation Efficiency in Pyridine‐Anchored Phthalocyanine‐Sensitized Solar Cells by Linker Elongation

“…The performance of Pc‐sensitized DSSCs has significantly improved by electronic push‐pull structure, steric suppression of aggregation, and optimization of adsorption sites ,. Previously, we reported an overall PCE of 6.4 % in DSSCs employing asymmetrical PcS20 decorated with short alkoxyl chain .…”

Methodologies in Spectral Tuning of DSSC Chromophores through Rational Design and Chemical-Structure Engineering

“…The primary components of DSSCs include a wide band gap mesoporous semiconductor deposited on a conducting glass substrate, a dye sensitizer, an electrolyte containing a redox couple/shuttle, and a counter electrode. The basic working principle of a DSSC and its essential properties has been well documented [28,30,48]. Depicted in Figure 1 is a schematic of the working principles of typical DSSCs.…”