2006
DOI: 10.1103/physrevb.74.075407
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Emission of correlated electron pairs from solid surfaces

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Cited by 36 publications
(40 citation statements)
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“…However, the measured carbon-carbon distance in benzene is 0.142 nm for all bonds, which is roughly the average length of a single and a double bond. This equivalence of all bonds in benzene was explained by Linus Pauling in 1931 within a quantum-mechanical treatment of the benzene ring (Pauling, 1960). The ground state is a quantummechanical superposition of the two possible configurations for the double bonds, as shown schematically in Fig.…”
Section: A the Carbon Atom And Its Hybridizationsmentioning
confidence: 95%
See 1 more Smart Citation
“…However, the measured carbon-carbon distance in benzene is 0.142 nm for all bonds, which is roughly the average length of a single and a double bond. This equivalence of all bonds in benzene was explained by Linus Pauling in 1931 within a quantum-mechanical treatment of the benzene ring (Pauling, 1960). The ground state is a quantummechanical superposition of the two possible configurations for the double bonds, as shown schematically in Fig.…”
Section: A the Carbon Atom And Its Hybridizationsmentioning
confidence: 95%
“…Therefore, the overlap corrections simply yield a renormalization of the NNN hopping amplitudes. The hopping amplitudes may be determined by fitting the energy dispersion (21) obtained within the tight-binding approximation to those calculated numerically in more sophisticated band-structure calculations (Partoens and Peeters, 2006) or to spectroscopic measurements (Mucha-Kruczyński et al, 2008). These yield a value of t ' À3 eV for the NN hopping amplitude and t 0 NNN ' 0:1t, which justifies the above-mentioned expansion for t 0 NNN =t ( 1.…”
Section: A Formal Solutionmentioning
confidence: 98%
“…The final two-electron state |3,4 includes the Coulomb correlation between the one-electron states |3 and |4 (as described in detail in Ref. 10).…”
Section: Formalism and Modelmentioning
confidence: 99%
“…With this in mind it becomes clear that DPE is particular sensitive to the electron-electron interaction. Moreover, a theoretical study on the DPE emission from a Cu(100) surface clearly showed that the exchange-correlation hole manifests itself in the angular distribution of the coincidence intensity [10][11][12]. The power of DPE has also been recognized in studies of atomic or molecular targets [13][14][15].…”
Section: Figure 2 Schematic Behavior Of the Pair Correlation Functionmentioning
confidence: 96%