A novel method is presented to validate the dispersion of a-alumina nanoparticles within a polymer matrix, as well as to create a calibration for filler particle volume fraction identification. Using photo-stimulated luminescence spectroscopy (PSLS), spectral information from a-alumina-filled epoxy nanocomposites consisting of varying volume fraction quantities of alumina nanoparticles was collected and analyzed. Surface contour maps of each nanocomposite were created by comparing integrated intensity data from the R1 curve of a-alumina throughout each specimen. These maps show satisfactory dispersion of alumina in the 5 and 25% volume fraction composites, whereas agglomerations were detected in various regions of the 38% nanocomposite, establishing the capability of this method to characterize photo-luminescent particle dispersion. This new approach also provides high spatial resolution, which can be used to determine the exact locations of voids, inclusions and/or agglomerations, while also predicting the volume percentage of photo-luminescent particle content within a specimen, lending itself as a quality control method in the manufacturing of these composites. Keywords: alumina nanocomposites; nanoparticle dispersion; photo-stimulated luminescence spectroscopy
INTRODUCTIONThermosetting polymers, such as epoxy resins, are currently being used in aerospace applications because of the ease for which their molecular structure can be modified, as well as their ability to sufficiently bond with various filler materials. 1 Typically, un-reinforced epoxies show poor resistance to crack initiation and propagation. 2 As a result, epoxies are commonly reinforced with filler particles, or modifiers, that alter their molecular structure by increasing the already dense cross-linked network structure of the epoxy, resulting in improved mechanical properties, such as strength, stiffness and toughness.Recent research has indicated that using nano-sized particles improves the stiffness, strength and toughness of a polymer without sacrificing the thermomechanical properties. 2,3 In addition, nanoparticles have a higher specific surface area than micron-sized particles, as more of these particles can be integrated within a specific volume, enabling an overall increase in the mechanical properties of the matrix. 1,4,5 Commonly embedded nanoparticles include aluminum oxide, 6-8 , calcium silicate 6 and titanium oxide. 6,9 With the improvement in mechanical properties, these nanocomposites have applications as ballistic materials with high-impact resistance. 10,11 Owing to a high dielectric strength, alumina-filled epoxy composites are also used in high-voltage applications, such as the encapsulation of ferroelectric elements for shock depoling. 12