The southern West Junggar terrane in the south‐western Central Asian Orogenic Belt (CAOB) is mainly composed of accretionary complexes and characterized by widespread outcrops of ophiolitic mélanges in the Barleik, Mayile, and Tangbale (BMT) areas, representing the site of consumption of the Junggar–Balkhash Ocean. However, due to a lack of comprehensive synthesis of the ophiolitic mélanges, the early evolution of the Junggar–Balkhash Ocean remains poorly understood. This paper first focuses on the little‐known Barleik ophiolitic blocks and associated pillow basalts and then integrates the Barleik, Mayile, and Tangbale ophiolitic mélanges into one model. Mineral and whole‐rock chemistry suggests that the Barleik ophiolitic blocks, including serpentinized dunite, clinopyroxenite, and gabbro, show supra‐subduction zone (SSZ) affinities, as indicated by high Cr# values (76–78) in spinels and strong depletion in Nb, Ta, Zr, and Hf, whereas the Barleik pillow basalts are alkaline and have high TiO2 contents (2.82–3.42 wt.%) and Nb–Ta enrichment, similar to ocean‐island basalt (OIB) lavas. Combined with published chronological and chemical data from ophiolites, metamorphic rocks, and arc plutons, we propose that the BMT Ediacaran to middle Cambrian ophiolitic gabbros were formed in a SSZ environment, implying a single Mariana‐type arc system within the Junggar–Balkhash Ocean, which was coeval with an Andean‐type arc system in the Kyrgyz North Tianshan, supporting an archipelagic model for the south‐western CAOB. By contrast, the BMT OIB‐type basalts are early Silurian in age, much younger than the SSZ‐type ophiolites, and can be interpreted as relicts of seamounts. Thus, a model involving the Ediacaran to Ordovician intra‐oceanic subduction and late Silurian to Early Devonian seamount accretion is helpful for clarifying the different components of the accretionary complexes in the southern West Junggar terrane.