Enantiomer Recognition Based on Chirality Transfer from Chiral Amines to Ternary Dynamic Covalent Systems
Liangpeng Wang,
Tingting Gao,
Jijun Yan
et al.
Abstract:Enantiomer recognition is usually required in organic synthesis and materials and life sciences. This paper describes an enantiomer recognition method based on ternary dynamic covalent systems constructed via the complexation of chiral amines with a chiral boronate derived from 1,4-phenylenediboric acid and an L-DOPAmodified naphthalenediimide. The ternary systems aggregate into chiral assemblies driven by π−π interactions, and the chirality is transferred from the chiral amines to assemblies with high stereos… Show more
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