Encapsulated peroxophosphotungstates catalyst into magnetic MOF: Magnetically recoverable heterogeneous high efficiency desulfurization catalyst

Peroxomolybdate@MOFs as effective catalysts for oxidative desulfurization of fuels: correlation between MOF structure and catalytic activity

“…However, in the next step, the peroxo structure must be re-generated by the interaction of H 2 O 2 oxidant via hydroxyl radicals formation, making the amount of H 2 O 2 an important parameter for catalyst efficiency as suggested previously in the literature on the analogous peroxotungstate PW 4 . 64,77…”

“…However, in the next step, the peroxo structure must be re-generated by the interaction of H 2 O 2 oxidant via hydroxyl radicals formation, making the amount of H 2 O 2 an important parameter for catalyst efficiency as suggested previously in the literature on the analogous peroxotungstate PW 4 . 64,77 The effect of PMo 4 amount was also studied to perform the desulfurization of model diesel using the optimized amount of H 2 O 2 (0.78 mmol) and [BMIM]PF 6 solvent. As shown in Fig.…”