2024
DOI: 10.1021/jacs.4c10890
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Encasing Triaryltriazine with a Bulky Chiral Cap: Luminescent Chiral Crystalline Molecular Rotors with Modulation of Solid-State Chiroptical Properties Mediated by Molecular Rotation

Namhee Kim,
Pingyu Jiang,
Ryunosuke Tomita
et al.

Abstract: A novel structural motif for luminescent chiral crystalline molecular rotors with chiroptical properties correlated with the rotational motion in crystalline media is presented. This scaffold incorporates bulky chiral caps consisting of a homochiral binaphthyl moiety with a triisopropylsilyl (TIPS) group into triaryltriazine, as confirmed by single-crystal X-ray diffraction (XRD) analysis. Variable-temperature solid-state 2 H NMR studies revealed a 4-fold rotation of the phenylenes occurred in the rotor crysta… Show more

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