We investigate bound states in the one-dimensional two-particle Bose-Hubbard model with an attractive (V > 0) impurity potential. This is a one-dimensional, discrete analogy of the hydrogen negative ion H − problem. There are several different types of bound states in this system, each of which appears in a specific region. For given V , there exists a (positive) critical value Uc1 of U , below which the ground state is a bound state. Interestingly, close to the critical value (U Uc1), the ground state can be described by the Chandrasekhar-type variational wave function, which was initially proposed for H − . For U > Uc1, the ground state is no longer a bound state. However, there exists a second (larger) critical value Uc2 of U , above which a molecule-type bound state is established and stabilized by the repulsion. We have also tried to solve for the eigenstates of the model using the Bethe ansatz. The model possesses a global Z2-symmetry (parity) which allows classification of all eigenstates into even and odd ones. It is found that all states with odd-parity have the Bethe form, but none of the states in the even-parity sector. This allows us to identify analytically two odd-parity bound states, which appear in the parameter regions −2V < U < −V and −V < U < 0, respectively. Remarkably, the latter one can be embedded in the continuum spectrum with appropriate parameters. Moreover, in part of these regions, there exists an evenparity bound state accompanying the corresponding odd-parity bound state with almost the same energy.