Energetics of La₂O₃–HfO₂–SiO₂ Glasses

Abstract

A series of La2O3–HfO2–SiO2 glasses, approximately along the join 0.73SiO2–0.27(xHfO2–(1−x)La2O3), 0<x<0.3), was prepared using containerless processing techniques (aerodynamic levitation combined with laser heating in oxygen). The enthalpy of formation and enthalpy of vitrification at 25°C were obtained from drop solution calorimetry of these glasses and appropriate crystalline compounds in a molten lead borate (2PbO–B2O3) solvent at 702°C. The enthalpy of formation from crystalline oxides was exothermic and became less exothermic with increasing HfO2 content. Heat contents were measured by transposed temperature drop calorimetry and depended linearly on the HfO2 content. Differential scanning calorimetry showed that both the onset glass transition and the onset crystallization temperature of these glasses increased with increasing HfO2 content. Upon slow cooling in air, the glasses crystallized to a mixture of baddeleyite, cristobalite, lanthanum disilicate, and hafnon.

Study on optical properties of La2O3–TiO2–Nb2O5 glasses prepared by containerless processing

“…This problem restricts its wider application in optical devices [1]. The polynary system shows larger glass-forming region, which can be prepared into bigger glass with high refractive index [18][19][20]. 20La 2 O 3 -(80 À x)TiO 2 -xNb 2 O 5 ternary system glasses have been successfully prepared with diameters larger than 3 mm by aerodynamic levitation.…”

Ab initioenergetics of lanthanum substitution in ferroelectric bismuth titanate

“…f , (per formula unit) of BIT, BLT (x = 0.25, 0.75) and related binary oxides. The values in parentheses refer to experimental measurements (E)[34,35] or other previous calculations (T)[26,25,36].…”