We highlight a dynamical anomaly in which the rate of relaxation towards thermal equilibrium in a bipartite quantum system violates the standard linear-response (Kubo) formulation, even when the underlying dynamics is highly chaotic. This anomaly originates from an ℏ-dependent sparsity of the underlying quantum network of transitions. Using a minimal bi-partite Bose-Hubbard model as an example, we find that the relaxation rate acquires an anomalous ℏ dependence that reflects percolation-like dynamics in energy space.