Food
waste is a promising resource for the production of fuels
and chemicals. However, increasing plastic contamination has a large
impact on the efficiency of conversion for the more established biological
routes such as anaerobic digestion or fermentation. Here, we assessed
a novel route through the hydrothermal liquefaction (HTL) of a model
waste (pistachio hulls) and polypropylene (PP). Pure pistachio hulls
gave a biocrude yield of 34% (w/w), though this reduced to 16% (w/w)
on the addition of 50% PP in the mixture. The crude composition was
a complex blend of phenolics, alkanes, carboxylic acids, and other
oxygenates, which did not change substantially on the addition of
PP. Pure PP does not breakdown at all under HTL conditions (350 °C,
15% solids loading), and even with biomass, there is only a small
synergistic effect resulting in a conversion of 19% PP. This conversion
was enhanced through using typical HTL catalysts including Fe, FeSO
4
·7H
2
O, MgSO
4
·H
2
O, ZnSO
4
·7H
2
O, ZSM-5, aluminosilicate,
Y-zeolite, and Na
2
CO
3
; the conversion of PP
reached a maximum of 38% with the aluminosilicate, for example. However,
the PP almost exclusively broke down into a solid-phase product, with
no enhancement of the biocrude fraction. The mechanism was explored,
and with the addition of the radical scavenger butylated hydroxytoluene
(BHT), the conversion of plastic reduced substantially, demonstrating
that radical formation is necessary. As a result, the plastic conversion
was enhanced to over 50% through the addition of the co-solvent and
hydrogen donor, formic acid, and the radical donor, hydrogen peroxide.
The addition of formic acid also changed the crude composition, including
more carboxylic acids and oxygenated species than the conversion of
the biomass alone; however, the majority of the carbon distributed
to the volatile organic gas fraction producing an array of short-chain
volatile hydrocarbons, which potentially could be repolymerized as
a polyolefin or combined with the biocrude for further processing.
Catalytic HTL was therefore shown to be a promising method for the
valorization of polyolefins with biomass under typical HTL conditions.