During the last 50 years, the vast majority of European countries have relied on coal and imported carbon-containing fuels to meet their growing electricity demand. Coal is the only fossil fuel in significant reserves across Europe. However, the pressing threat of radical climate change and the looming depletion of fossil fuels necessitate a structural transformation from a conventional centralized fossil fuel-based electricity generation system to an innovative decentralized system based on zero carbon (green) energy resources. In this context, one important issue for communities operating coal-based Thermal Power Stations (TPS) nearing retirement is whether the European Union (EU) policy can ensure a socially just development of the coal mining areas during the coal phase-out. The objective is to avoid a decline in living standards and mass immigration. In response to the EU’s decarbonization policy, the Greek state has recently decided to retire the lignite-based West Macedonia TPS, which has been in operation since the 1970s. Since its establishment in August 1950, the (initially State-controlled) Greek Public Power Corporation (PPC) has undertaken the responsibility to operate the quarries and the six local TPS, offering approximately 25,000 direct and indirect jobs. Over the last 50 years, the extraction of lignite and the operation of the 4500 MWe TPS of West Macedonia has been the primary economic activity, accounting for nearly 45% of the entire Region’s GDP. While both the Greek state and the EU have prepared and presented plans to financially support local communities and encourage new private and public investments, local citizens remain anxious about their future. The present study investigates the attitude of young scientists towards the forthcoming radical changes linked to the green transition in seriously affected EU Regions, with a focus on West Macedonia. The proposed analysis in West Macedonia reveals the skepticism of young people regarding the speed of the green transition and concerns about significant migration and potential brain drain. On the other hand, the implementation of EU initiatives, including the involvement of young scientists in the planned new green energy-related activities, offers a promising alternative solution. This engagement can lead to the successful integration of local communities into the sustainable and green future envisioned by the EU.