The interactions by which ions lose their energy in silicon are investigated at the microscopic level. This theoretical study put in evidence that the ionization could also represent a source of structural defects, and, contrary to the processes initiated by elementary particles, could generate extended primary defects, as, e.g. four‐fold coordinated defects, due to the simultaneous breaking of bonds for more neighbouring atoms in the lattice in a single interaction, in the ionisation core. The average energy transferred per atom is calculated, and also the energy spent by ionisation. The time dependence of the temperature in the ionisation core is derived in some simplifying assumptions. These contributions were not considered yet in the studies of degradation of silicon detectors in radiation fields and could account for the discrepancies observed between models and measurements at microscopic versus device level for hadrons and ions. (© 2009 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)