1982
DOI: 10.1063/1.330018
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Energy gap versus alloy composition and temperature in Hg1−xCdxTe

Abstract: We have used the data from 22 different studies to derive a new empirical expression for the energy band gap (Eg) of Hg1−xCdxTe: Eg =−0.302+1.93x+5.35(10−4)T(1−2x) −0.810x2+0.832x3. This expression is valid over the full composition range and for temperatures from 4.2 to 300 K. The standard error of estimate is 0.013 eV, which is at least 15% better than that of previously reported expressions.

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Cited by 626 publications
(193 citation statements)
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“…9,10 This study extends upon those by reporting that HSE outperforms standard DFT on the electronic structure of the II-VI alloy Hg 1−x Cd x Te by reproducing the experimental crossover at x = 0.17 (Ref. 11 ) transitioning from a semimetallic alloy with band inversion to a gapped semiconducting alloy. HSE also achieves a valence band offset (VBO) of 0.53 eV for HgTe/CdTe(001) agreeing with the more recent experimental data and settling a controversy on the VBO.…”
Section: Introductionsupporting
confidence: 49%
“…9,10 This study extends upon those by reporting that HSE outperforms standard DFT on the electronic structure of the II-VI alloy Hg 1−x Cd x Te by reproducing the experimental crossover at x = 0.17 (Ref. 11 ) transitioning from a semimetallic alloy with band inversion to a gapped semiconducting alloy. HSE also achieves a valence band offset (VBO) of 0.53 eV for HgTe/CdTe(001) agreeing with the more recent experimental data and settling a controversy on the VBO.…”
Section: Introductionsupporting
confidence: 49%
“…7 Cd o . 3 Ta at 300 K The dotted cUlVe represents the numerical result with an effective carrier temperature of Teft =360 K to the absorption edge.…”
Section: Methodsmentioning
confidence: 99%
“…The temperature and composition dependence of the Hg 1-x Cd x Te energy gap is given by the expression [7]:…”
Section: Sensitive Structures Based On Hg 1-x CD X Te and Their Electmentioning
confidence: 99%