“…As we have discussed in the previous section, although some of the lead-free materials have exhibited superior thermal energy harvesting performance to that of the lead-based pyroelectric materials, the lead-based materials show superior FoMs for applications such as infrared sensors, which make them an excellent choice for commercial sensor application. In the quest for excellent materials for PyEH application, a plethora of studies have been reported on PZT- and PMN-PT-based ceramics and their thin films [64,85,108,114,115,116,117,118,119,120,121]. The phase transformations of the ceramics play a huge role in the PyEH energy density and efficiency.…”