The 20Ne(3He,d)21Na reaction has been studied at 16 MeV bombarding energy. The emitted deuterons have been analysed in a double focusing magnet. Levels in 21Na were deduced. Furthermore the 20Ne(p,γ)21Na reaction has been investigated using a 44 cm3 Ge(Li) detector. Gamma ray branching ratios and life times have been measured at the 1 169, 1 311 and 1 504 keV resonances. The experimental information is discussed in terms of the Nilsson strong-coupling model and recent shell model calculations.