Passive radiative cooling materials, which provide cooling
without
consuming electricity, are widely recognized as an important technology
for reducing greenhouse gas emissions and delivering thermal comfort
to less industrialized communities. Optimizing thermal and optical
properties is of primary importance for these materials, but for real-world
utilization, ease of application and scalability also require significant
emphasis. In this work, we embed the biomaterial hydroxyapatite, in
the form of nanoscale fibers, within an oil-based medium to achieve
passive cooling from an easy-to-apply paint-like solution. The chemical
structure and bonding behaviors of this mixture are studied in detail
using FTIR, providing transferable conclusions for pigment-like passive
cooling solutions. By reflecting 95% of solar energy and emitting
92% of its radiative output through the atmospheric transparency window,
this composite material realizes an average subambient cooling performance
of 3.7 °C in outdoor conditions under a mean solar irradiance
of 800 W m–2. The inflammability of the material
provides enhanced durability as well as unique opportunities for recycling
which promote circular economic practices. Finally, the surface structure
can be easily altered to tune bonding behaviors and hydrophobicity,
making it an ideal passive cooling coating candidate for outdoor applications.