2007
DOI: 10.1063/1.2764077
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Energy transfer of highly vibrationally excited naphthalene. I. Translational collision energy dependence

Abstract: Energy transfer between highly vibrationally excited naphthalene and Kr atom in a series of translational collision energies (108-847 cm(-1)) was studied separately using a crossed-beam apparatus along with time-sliced velocity map ion imaging techniques. Highly vibrationally excited naphthalene in the triplet state (vibrational energy: 16,194 cm(-1); electronic energy: 21,400 cm(-1)) was formed via the rapid intersystem crossing of naphthalene initially excited to the S(2) state by 266 nm photons. The collisi… Show more

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Cited by 16 publications
(13 citation statements)
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References 37 publications
(32 reference statements)
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“…30 However, in order to compare the energy transfer of 2-methylnaphthalene in the same translational collision en-a͒ Also at Department of Chemistry, National Taiwan University, Taipei 10617, Taiwan. 30 However, in order to compare the energy transfer of 2-methylnaphthalene in the same translational collision en-a͒ Also at Department of Chemistry, National Taiwan University, Taipei 10617, Taiwan.…”
Section: Methodsmentioning
confidence: 99%
See 1 more Smart Citation
“…30 However, in order to compare the energy transfer of 2-methylnaphthalene in the same translational collision en-a͒ Also at Department of Chemistry, National Taiwan University, Taipei 10617, Taiwan. 30 However, in order to compare the energy transfer of 2-methylnaphthalene in the same translational collision en-a͒ Also at Department of Chemistry, National Taiwan University, Taipei 10617, Taiwan.…”
Section: Methodsmentioning
confidence: 99%
“…[30][31][32] Only a brief description is described here. Electronic mail: ckni@po.iams.sinica.edu.tw.…”
Section: Methodsmentioning
confidence: 99%
“…55 The same time-resolved UV absorption spectroscopy was used for studying collisional relaxation of benzene 56 and hexafluorobenzene. [57][58][59] Recently, Ni et al have used a molecular beam apparatus with a time-sliced velocity map ion imaging technique to study collisional energy transfer from azulene, 60 and naphthalene [61][62][63][64] and its derivatives, 65 in collisions with monoatomic [60][61][62][63]65 as well as polyatomic 64 bath gases. Several other experimental techniques have also been used, namely, kinetically controlled selective ionization (KCSI) detection, 66,67 infrared multiphoton absorption (IRMPA) coupled with time resolved infrared fluoresence (IRF), [68][69][70] and supersonic free jet expansion.…”
Section: Introductionmentioning
confidence: 99%
“…1, 2 Among the various investigations in the field, the detailed mechanisms of energy redistribution following an electronic transition have been particularly scrutinized, 3,4 but rare gases have also proved suitable as cold media for various applications ranging from spectroscopy 5,6 to controlled chemical reactions. 7 From the theoretical perspective, van der Waals complexes are ideal to benchmark quantum chemistry methods aimed at evaluating dispersion-dominated potential energy surfaces.…”
Section: Introductionmentioning
confidence: 99%