Energy Transfer Processes of Chemiluminescence Reaction Systems with Cerium(IV) Ions and Their Analytical Application: A Review

Kaczmarek, Małgorzata

doi:10.1007/s10895-015-1529-x

Cited by 11 publications

(7 citation statements)

References 72 publications

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“…Figure S2a shows the FL emission spectra. The systems GQD–Ce(IV), GQD–Ce(IV)–NaHSO 3 , and GQD–Ce(IV)–NaHSO 3 –Tyr share the same luminophores with GQD, and the emission peak of the Ce(IV)–Na 2 SO 3 system is different with GQD, which is similar to the FL of excited Ce(III) at 360 nm …”

Section: Resultsmentioning

confidence: 76%

“…The systems GQD-Ce(IV), GQD-Ce(IV)-NaHSO 3 , and GQD-Ce(IV)-NaHSO 3 -Tyr share the same luminophores with GQD, and the emission peak of the Ce(IV)-Na 2 SO 3 system is different with GQD, which is similar to the FL of excited Ce(III) at 360 nm. [28] To study the free radicals generated in the CL system, the effects of different active oxygen radical scavengers on the CL intensity of the GQD-Ce(IV)-NaHSO 3 system were investigated. The results are shown in Figure S2b.…”

Section: Possible CL Mechanismmentioning

confidence: 99%

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Graphene quantum dot‐enhanced chemiluminescence through energy and electron transfer for the sensitive detection of tyrosine

Pang

Han

et al. 2018

J Chinese Chemical Soc

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Graphene quantum dots (GQD) could significantly enhance the chemiluminescence (CL) reaction of Ce(IV) with NaHSO3 through energy and electron transfer. The chemiluminescence resonance energy transfer (CRET) occurred between SO2*/1O2 and GQD, and radiative electron–hole annihilation came from the combining of the hole‐injected GQD (GQD•+) and electron‐injected GQD (GQD•–). Tyrosine (Tyr) is easily oxidized by OH• and Ce(IV), which results in the decrease of OH• and Ce(IV), and the CL intensity of the GQD–Ce(IV)–NaHSO3 system is inhibited by Tyr. In this way, the GQD‐based CL as a sensitive and selective method was applied for the detection of Tyr in the range 0.02–8.00 μM with the detection limit of 4.0 nM. The method was applied to the determination of Tyr in food samples with satisfactory results.

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Section: Resultsmentioning

confidence: 76%

Section: Possible CL Mechanismmentioning

confidence: 99%

Graphene quantum dot‐enhanced chemiluminescence through energy and electron transfer for the sensitive detection of tyrosine

Pang

Han

et al. 2018

J Chinese Chemical Soc

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“…The unstable energy‐rich Ce(III)* was produced from the redox reaction between CuNCs and Ce(IV). A perfect overlap between FL emission spectrum of the Ce(III)* and the excitation spectrum of the CuNCs, and a suitable distance between Ce(III)* and CuNCs meant the possible occurrence of CL resonance energy transfer (CRET) between Ce(III)* as energy donors and CuNCs as acceptors, and the formation of CuNCs*, a CL produced.

Ce {(III)}^{*} + CuNCs \to {CuNCs}^{*} \to CuNCs + hν ((), 480 nm)

…”

Section: Resultsmentioning

confidence: 99%

“…between Ce(III)* as energy donors and CuNCs as acceptors, [32,33] and the formation of CuNCs*, a CL produced.…”

Section: Possible CL Mechanismmentioning

confidence: 99%

Chemiluminescence of copper nanoclusters and its application for trihexyphenidyl hydrochloride detection

Chen

Zhang

et al. 2018

Luminescence

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Chemiluminescence (CL) of copper nanoclusters (CuNCs) induced by cerium (IV) (Ce(IV)) or potassium permanganate (KMnO ) in acidic medium was observed. The potential application of CuNCs CL in analytical chemistry was also demonstrated using trihexyphenidyl hydrochloride (THP) as an example based on its enhancing CL intensity for the CuNCs-Ce(IV)/KMnO systems. The excited state of the CuNCs acted as a luminophore in the CuNCs-Ce(IV) system, while CuNCs played the role of reductant in the CuNCs-KMnO system. The increased CL intensity for Ce(IV)-CuNCs system was proportional to the THP concentrations in the range of 0.1 to 10.0 μM. The detection limit was 49.0 nM and the relative standard deviation was 2.2% for 2.0 μM THP (n = 11). The proposed method was applied to detect THP in pharmaceutical formulations and human plasma samples.

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“…[9][10][11][12][13][14] The main advantages associated with the CL detection system are simplicity of the procedure and inexpensive instrumentation in addition to high sensitivity and a wide dynamic range. Moreover, the advantages of flow injection (FI) methods are incorporated into the CL method to provide automated, rapid, and reproducible analyses.…”

Section: Introductionmentioning

confidence: 99%

A Flow Method for Chemiluminescence Determination of Antimony(III) and Antimony(V) Using a Rhodamine B-Cetyltrimethylammonium Chloride Reversed Micelle System Following On-Line Extraction

et al. 2016

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A rapid and sensitive flow method, based on the combination of on-line solvent extraction with reversed micellar mediated chemiluminescence (CL) detection using rhodamine B (RB), was developed for the determination of antimony(III) and antimony(V) in aqueous samples. The on-line extraction procedure involved ion-pair formation of the antimony(V) chloro-complex anion with the protonated RBH + ion and its extraction from an aqueous hydrochloric acid solution into toluene, followed by phase separation using a microporous membrane. When in a flow cell of a detector, the ion-pair in the extract driven was mixed with the reversed micellar solution of cetyltrimethylammonium chloride in 1-hexanol-cyclohexane/water (0.60 mol dm -3 H2SO4) containing cerium(IV), its uptake by the reversed micelles and the subsequent CL oxidation of RB with Ce(IV) occurred easily, then the produced CL signal was measured. Using the proposed flow method under the optimized experimental conditions, a detection limit (DL) of 0.35 μmol dm -3 and a linear calibration graph with a dynamic range from DL to 16 μmol dm -3 were obtained for Sb(V) with a precision of 1.4% relative standard deviation (n = 5) at the Sb(V) concentration of 8.2 μmol dm -3. The present method was successfully applied to the determination of Sb(V) in water samples and to the differential determination of Sb(III) and Sb(V) in copper electrolyte industrial samples, where total antimony Sb(III) + Sb(V) was determined after oxidation of Sb(III) to Sb(V) with Ce(IV) and Sb(III) was calculated by difference, for which the DL was almost the same as that for Sb(V).

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Energy Transfer Processes of Chemiluminescence Reaction Systems with Cerium(IV) Ions and Their Analytical Application: A Review

Cited by 11 publications

References 72 publications

Graphene quantum dot‐enhanced chemiluminescence through energy and electron transfer for the sensitive detection of tyrosine

Graphene quantum dot‐enhanced chemiluminescence through energy and electron transfer for the sensitive detection of tyrosine

Chemiluminescence of copper nanoclusters and its application for trihexyphenidyl hydrochloride detection

A Flow Method for Chemiluminescence Determination of Antimony(III) and Antimony(V) Using a Rhodamine B-Cetyltrimethylammonium Chloride Reversed Micelle System Following On-Line Extraction

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