Engineering design of N-doped Co3O4 nanofibers as sulfur host for highly stable cathode materials

Ma, Wenming; Zhang, Xiaojuan; Meng, Yonggang; Zhao, Jun

doi:10.1007/s11581-021-04345-x

Cited by 3 publications

(1 citation statement)

References 27 publications

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“…Catalytic materials refer to a class of substances that improve conversion and accelerate redox reactions by assisting active materials to accept ions or electrons. 211–213 The adsorption-catalysis synergy of the catalytic materials can not only trap soluble polysulfides on their surfaces, but also reduce the overpotential in LSBs, endowing carbon-based sulfur storage carriers with greater possibilities. In this section, the research on the modification of the carbon matrix using metal compounds (metal oxides, metal sulfides, metal carbides and metal hydroxides), non-metallic compounds, single metal nanoparticles and some emerging catalytic materials for sulfur storage is summarized, and their synergy with the porous structure and heteroatom doping is also involved.…”

Section: Catalytic Materials Modified Bdc-based Hostsmentioning

confidence: 99%

Renewable biomass-derived carbon-based hosts for lithium–sulfur batteries

Zhao

Chen

et al. 2022

Sustainable Energy Fuels

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Section: Catalytic Materials Modified Bdc-based Hostsmentioning

confidence: 99%

Renewable biomass-derived carbon-based hosts for lithium–sulfur batteries

Zhao

Chen

et al. 2022

Sustainable Energy Fuels

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Defect spinel oxides for electrocatalytic reduction reactions

Liu,

Guo,

Liu

et al. 2023

Nano Res.

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In Situ Growth of Carbon Nanotubes on Iron Phosphate and Doped with Nitrogen and Selenium for Lithium–Sulfur Batteries

Ouyang,

You,

Zheng

et al. 2024

ACS Appl. Nano Mater.

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Lithium−sulfur (Li−S) batteries have been considered as one of the effective alternative energy systems to commercial lithium-ion batteries (LIBs) due to their high theoretical energy density (2600 Wh kg −1 ), high theoretical specific capacity (1675 mAh g −1 ), low cost, and abundant reserves of sulfur. However, intrinsic challenges, such as severe shuttle effect, low conductivity, and significant volume expansion, hinder their large-scale application. In this study, a novel composite (CNT/FP-N, Se), which in situ grown with carbon nanotubes (CNTs) and doped with N, Se elements, has been synthesized by utilizing commercial ferric phosphate (FP) as a precursor. Benefitting from the synergistic effects of abundant adsorption active sites of CNTs and the catalytic effects of N and Se, the shuttle effect of lithium polysulfides (LPS) can be effectively inhibited, leading to an enhancement of Li−S batteries when the CNT/FP-N, Se is utilized as separator modifier. The charge/ discharge platforms can be well maintained from 0.1 to 5 C, and a capacity of 617 mAh g −1 at 5 C can be acquired. Notably, an initial capacity of 990.7 mAh g −1 at 1 C can be obtained, with a retention of 711.3 mAh g −1 after 500 cycles, corresponding to a capacity loss rate of only 0.056% per cycle. This work provides a feasible scheme for FP application in next-generation low-cost energy systems.

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Engineering design of N-doped Co3O4 nanofibers as sulfur host for highly stable cathode materials

Cited by 3 publications

References 27 publications

Renewable biomass-derived carbon-based hosts for lithium–sulfur batteries

Renewable biomass-derived carbon-based hosts for lithium–sulfur batteries

Defect spinel oxides for electrocatalytic reduction reactions

In Situ Growth of Carbon Nanotubes on Iron Phosphate and Doped with Nitrogen and Selenium for Lithium–Sulfur Batteries

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