Engineering metal-organic frameworks for efficient photocatalytic conversion of CO2 into solar fuels

Ezugwu, Chizoba I.; Liu, Shengwei; Li, Chuanhao; Zhuiykov, Serge; Roy, Soumyajit; Verpoort, Francis

doi:10.1016/j.ccr.2021.214245

Cited by 89 publications

(46 citation statements)

References 249 publications

(335 reference statements)

Supporting

Mentioning

Contrasting

Order By: Relevance

“…MOFs have advanced photoreduction of CO 2 . [284,[305][306][307][308][309][310][311][312][313][314][315][316][317][318][319][320][321][322] The reaction requires a ZIF materials with good light absorption. Most of the reported ZIF materials lack high visible-light absorption.…”

Section: Hydrogenation For Comentioning

confidence: 99%

Removal of carbon dioxide using zeolitic imidazolate frameworks: Adsorption and conversion via catalysis

Abdelhamid

2022

Applied Organom Chemis

View full text Add to dashboard Cite

Carbon dioxide (CO2) is one of the culprit causes of global climatic changes. Furthermore, the efficient separation of CO2 from other gaseous mixtures using zeolitic imidazolate framework (ZIF)‐based materials is vital for several processes such as flue gas separation, gas sweetening, and natural gas processing. ZIF‐based materials are emerging adsorbents and catalysts for CO2 gas removal via adsorption and conversion into valuable chemicals. ZIF‐based adsorbents with high‐adsorption/conversion efficiencies and tunable properties can be achieved by judicious synthesis and fabrication methods. We reviewed ZIF‐based materials for CO2 removal via adsorption and catalysis (e.g., cycloaddition, carboxylation, hydrogenation, N‐formylation, electrocatalysis, and photocatalysis). In addition, recent development methods such as membrane technologies and ways to improve the gas separation performance of ZIF membranes were highlighted. The prospective point of view to promote industrial applications and commercialization of ZIF‐based materials was briefly discussed. Once challenges such as low performance and reproducibility for ZIF‐based materials are solved, scalability and cost‐effectiveness should not become issues.

show abstract

Section: Hydrogenation For Comentioning

confidence: 99%

Removal of carbon dioxide using zeolitic imidazolate frameworks: Adsorption and conversion via catalysis

Abdelhamid

2022

Applied Organom Chemis

View full text Add to dashboard Cite

show abstract

“…MOFs have advanced photoreduction of CO2 [284,[305][306][307][308][309][310][311][312][313][314][315][316][317][318][319][320][321][322] . The reaction requires a ZIF materials with good light absorption.…”

Section: 5photocatalytic Reduction Of Co2mentioning

confidence: 99%

A Review on Removal of Carbon Dioxide (CO2) using Zeolitic Imidazolate Frameworks: Adsorption and Conversion via Catalysis

Abdelhamid

2022

Preprint

View full text Add to dashboard Cite

Carbon dioxide (CO2) is one of the culprit causes of global climatic changes. Furthermore, the efficient separation of CO2 from other gaseous mixtures using ZIFs-based materials is vital for several processes such as flue gas separation, gas sweetening, and natural gas processing. Zeolitic imidazolate frameworks (ZIFs)-based materials are emerging adsorbents and catalysts for CO2 gas removal via adsorption and conversion into valuable chemicals. ZIFs-based adsorbents with high adsorption/conversion efficiencies and tunable properties can be achieved by judicious synthesis and fabrication methods. We reviewed ZIF-based materials for CO2 removal via adsorption and catalysis (e.g., cycloaddition, carboxylation, hydrogenation, N-formylation, electrocatalysis, and photocatalysis). In addition, recent development methods such as membrane synthesis and ways to improve the gas separation performance of ZIF membranes were highlighted. The prospective point of view to promote industrial applications and commercialization of ZIF-based materials was briefly discussed. Once challenges such as low performance and reproducibility for ZIFs-based materials are solved, scalability and cost-effectiveness should not become issues.

show abstract

“…[7][8][9][10] In recent years, MOFs have been demonstrated to show potential in the photocatalytic eld, since their structural tunability allows them to exhibit catalytic activity in the photocatalytic process, enabling MOFs devoted to systematic and structural-dependent photocatalytic investigations. [11][12][13] Much effort has been made to improve the efficiency of MOF photocatalysts including structural engineering, modication and functionalization. [14][15][16] Among these, defect engineering has been documented to be an effective approach to tailor the photocatalytic behavior.…”

Section: Introductionmentioning

confidence: 99%

Tailoring defect-type and ligand-vacancies in Zr(iv) frameworks for CO₂ photoreduction

Wang

Cheng

et al. 2022

J. Mater. Chem. A

View full text Add to dashboard Cite

show abstract

Engineering metal-organic frameworks for efficient photocatalytic conversion of CO2 into solar fuels

Cited by 89 publications

References 249 publications

Removal of carbon dioxide using zeolitic imidazolate frameworks: Adsorption and conversion via catalysis

Removal of carbon dioxide using zeolitic imidazolate frameworks: Adsorption and conversion via catalysis

A Review on Removal of Carbon Dioxide (CO2) using Zeolitic Imidazolate Frameworks: Adsorption and Conversion via Catalysis

Tailoring defect-type and ligand-vacancies in Zr(iv) frameworks for CO₂ photoreduction

Contact Info

Product

Resources

About

Engineering metal-organic frameworks for efficient photocatalytic conversion of CO2 into solar fuels

Cited by 89 publications

References 249 publications

Removal of carbon dioxide using zeolitic imidazolate frameworks: Adsorption and conversion via catalysis

Removal of carbon dioxide using zeolitic imidazolate frameworks: Adsorption and conversion via catalysis

A Review on Removal of Carbon Dioxide (CO2) using Zeolitic Imidazolate Frameworks: Adsorption and Conversion via Catalysis

Tailoring defect-type and ligand-vacancies in Zr(iv) frameworks for CO2 photoreduction

Contact Info

Product

Resources

About

Tailoring defect-type and ligand-vacancies in Zr(iv) frameworks for CO₂ photoreduction