Engineering the structural formula of N-doped molybdenum carbide nanowires for the deoxygenation of palmitic acid

Abstract

The cleavage of C–O in palmitic acid is controlled by the self-assemblied MoxCNy nanowires with alterable structural formula.

Steerable Engineering of Nickel Molybdenum Carbonitride Nanostructures for Catalytic Regioselectivity Cleavage of C–O and C–C Bonds in Deoxygenation of Methyl Palmitate

“…However, increasing the Ni content only results in increasing the Ni 2 Mo 3 N content other than increasing the Mo 2+∼δ+ content, suggesting that Mo 2+∼δ+ species is affected by Ni, C, and N simultaneously, which further proves that electron transfer within Ni-Mo-C-N catalysts exists and there is an interaction within the nickel molybdenum carbonitrides. As is well-known, XPS analysis is related to the surface properties of catalysts; thus, it can be concluded that Ni 0.30 MoCN exhibits a better oxidation resistance . It can also partly present the situation of Mo species among the carbonitride catalysts. − It is well-known that Mo 2+∼δ+ species belongs to the carbonitrided Mo, which is related to the activity of the molybdenum-based carbonitrides.…”

“…As is well-known, XPS analysis is related to the surface properties of catalysts; thus, it can be concluded that Ni 0.30 MoCN exhibits a better oxidation resistance. 45 It can also partly present the situation of Mo species among the carbonitride catalysts. 46−50 It is well-known that Mo 2+∼δ+ species belongs to the carbonitrided Mo, which is related to the activity of the molybdenum-based carbonitrides.…”

“…51,52,55−57 However, the cleavage of C−C bonds is weak among Mo-based catalysts including the Mo 2 C catalyst, which is also in accordance with the activity and selectivity of the MoCN catalyst. 45,58 It can be concluded that the addition of Ni makes for the regioselectivity cleavage of C−C bonds adjacent to carbonyl groups at a certain degree. The related cleavage of C−C bonds over Ni x MoCN is dependent on the metallic sites of Ni species.…”

Co3Mo3N as an alternative for noble-metal catalysts in hydrodeoxygenation of methyl palmitate to diesel range hydrocarbons

“…Based on the characteristics of fatty acid and ester hydrogenation, catalysts including noble metals, transition-metal phosphides, transition-metal suldes, and transition-metal carbides have been widely developed. [11][12][13][14] However, there are some problems with these catalysts, such as the deactivation in the case of transition metal suldes/carbides and the high cost of noble metals. Recently, transition-metal nitride has been widely studied due to the lower cost and Pt-like properties in HDO of biomass resources.…”

Supercritical Water Gasification as Treatment for High Lipid Content Biomass in the Presence of Nickel Catalyst

“…From Table 3, aliphatic compounds such as cetene and heptadecane were detected in the liquid e uent obtained a er gasi cation at 2 wt% feed concentration. Chen et al (2020) reported the catalytic hydrodeoxygenation via decarbonylation of palmitic acid to produce cetene as one of its intermediate products. Heptadecane is a product of stearic acid deoxygenation, along with carbon dioxide.…”