Enhanced alcohol and H2O adsorption and separation performances by introducing pyridyl ligand in a MOF

In this paper, a novel Yb metal–organic frameworks {[Yb(L)(DMA)(H2O)]·(3H2O)}n (Yb‐MOF, H3L is 4‐(N,N′‐bis(4‐carboxylbenzyl)amino)benzenesulfonic acid) was synthesized by solvothermal reaction. Modified Yb‐MOF was prepared by the potassium permanganate method for removing the Cu(II) and As(V) from simulated wastewater. The optimal pH value of modified Yb‐MOF for Cu(II) and As(V) adsorption was 5, and the optimal dosage of adsorbent was 0.04 mg/10 ml by static adsorption test. Four isothermal adsorption models (Freundlich, Langmuir, Temkin, and Dubinin–Radushkevich models) were fitted and analyzed. The adsorption processes of Cu(II) and As(V) were consistent with Freundlich, Langmuir, and Temkin models. The highest Cu(II) and As(V) adsorption capacity are 59.418 and 81.169 mg/g, respectively. The adsorption kinetic model and thermodynamic analysis of the modified Yb‐MOF for Cu(II) and As(V) were studied. The results showed revealed that the pseudo‐second‐order kinetic had a higher correlation association with the Cu(II) and As(V) adsorption process, indicating that chemisorption was dominant in both processes. At 298 and 308 K, the Cu(II) and As(V) adsorption by modified Yb‐MOF is spontaneous.

show abstract

Synthesis, modification, and adsorption properties of Yb‐MOF: Kinetic and thermodynamic studies

Yin

Deng

et al. 2022

Applied Organom Chemis

View full text Add to dashboard Cite

show abstract

Review: Synthesis of metal organic framework-based composites for application as immunosensors in food safety

Pan

Yang

et al. 2023

Analytica Chimica Acta

View full text Add to dashboard Cite

Recent advances in removal of toxic elements from water using MOFs: A critical review

ALOthman

Shahid²

2022

Arabian Journal of Chemistry

View full text Add to dashboard Cite

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Enhanced alcohol and H2O adsorption and separation performances by introducing pyridyl ligand in a MOF

Cited by 5 publications

References 34 publications

Synthesis, modification, and adsorption properties of Yb‐MOF: Kinetic and thermodynamic studies

Synthesis, modification, and adsorption properties of Yb‐MOF: Kinetic and thermodynamic studies

Review: Synthesis of metal organic framework-based composites for application as immunosensors in food safety

Recent advances in removal of toxic elements from water using MOFs: A critical review

Contact Info

Product

Resources

About