As the world transitions toward a more sustainable energy future, energy storage power plants play an increasingly crucial role in integrating renewable energy sources into the grid. However, ensuring the safety of battery operations in these facilities remains a critical concern. Assessing battery safety operations (BSO) in energy storage power stations is complex multiple-attribute group decision-making (MAGDM) task. Recently, the logarithmic TODIM (LogTODIM) technique was introduced to handle MAGDM challenges. Single-valued neutrosophic sets (SVNSs) have also emerged as tool for managing fuzzy data in BSO risk assessments. This study proposes the single-valued neutrosophic number combined LogTODIM (SVNN-Com-LogTODIM) technique to address MAGDM within the framework of SVNSs. A numerical case study on BSO risk assessment in energy storage power stations is provided to demonstrate the SVNN-Com-LogTODIM technique through comparative analysis.