1994
DOI: 10.1063/1.112011
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Enhanced critical currents by CeO2 additions in directionally solidified YBa2Cu3O7

Abstract: The microstructure and critical currents of superconducting YBa2Cu3O7-Y2BaCuO5 composites with small CeO2 additions prepared using a directional solidification procedure have been investigated. The small CeO2 additions cause the decomposition of the Y2BaCuO5 phase leading to the formation of Y2O3 and BaCeO3. Experimental evidence is given for the subsequent nucleation of the Y2BaCuO5 phase on the Y2O3 particles. This new decomposition-nucleation mechanism leads to textured YBa2Cu3O7 having enhanced critical cu… Show more

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Cited by 142 publications
(87 citation statements)
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“…Almost the same effect has been reported in CeO 2 added YBCO [12]. It is worth mentioning that the size refinement of Y-211 is an increase in the nucleation site for Y-211.…”
Section: -3 Coarsening Of (Lre)-211 Particlessupporting
confidence: 63%
See 1 more Smart Citation
“…Almost the same effect has been reported in CeO 2 added YBCO [12]. It is worth mentioning that the size refinement of Y-211 is an increase in the nucleation site for Y-211.…”
Section: -3 Coarsening Of (Lre)-211 Particlessupporting
confidence: 63%
“…Here the addition of Pt (typically 0.1-0.5 wt.%) to the precursor powder is very effective for refinement of Y-211 in the liquid, which led to fine dispersion of Y-211 particle in the Y-123 superconducting matrix, hence high J c [11]. CeO 2 powder has been also used instead of Pt for cost-effective production [12]. The effect of Pt addition to the precursor pellet on microstructures will be discussed later.…”
Section: -2 Top-seeded Melt Growth (Tsmg) Processmentioning
confidence: 99%
“…Magnetic fields up to H = 50 kOe were applied parallel and perpendicular to the c-axis. The melttextured YBaCuO sample was prepared by top-seeding technique [7], with 25 wt.% of Y 2 BaCuO 5 (Y211), and the single crystalline YCaBaCuO sample was grown by the self-flux method [8]. The magnetization measurements were done with a Quantum Design SQUID magnetometer.…”
Section: Introductionmentioning
confidence: 99%
“…These sample types are referred as "NN", "NT", "TN" and "TT", where the first and second letters represent the manufacturers of the Y-123 and Y-211 precursor powders, respectively. All powder mixtures consisted, by weight, of 70 wt% Y-123 and 30 wt% Y-211 and an excess of 1.0 wt% cerium oxide (purity 99.9%, supplied by Alfa Aesar), CeO 2 , which inhibits the coarsening of Y-211 particles during melt processing and limits their size in the fully processed sample microstructure [20][21][22][23][24].…”
Section: Sample Productionmentioning
confidence: 99%