Polymer dielectrics have gained significant usage in electrical engineering due to their unique merits, such as good flexibility, easy processing, and low cost. However, it is a huge challenge that polymer dielectrics maintain high breakdown strength meanwhile high permittivity for enhanced energy density. Here, sandwiched polymer films are constructed for enhanced energy density. Increased permittivity has been achieved via blending BaTiO3@polyfluorosiloxane with a polymer as the top and bottom layer. Furthermore, the neat polymer as the middle layer is without critically sacrificing breakdown strength. The energy storage density increases from 7.8 J/cm3 of the neat polymer to 10.41 J/cm3 of the sandwich structure at 460 MV/m. This research offers a feasible route for fabricating capacitive films with enhanced energy density.