Enhanced ferroelectric and piezoelectric response in Mn-doped Bi0.5Na0.5TiO3–BaTiO3 lead-free film by pulsed laser deposition

Jin, Chengchao; Wang, Feifei; Leung, Chung Ming; Yao, Qiuyan; Tang, Yin; Wang, Tao; Shi, Wangzhou

doi:10.1016/j.apsusc.2013.06.114

Cited by 26 publications

(3 citation statements)

References 26 publications

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“…S / E at the maximum positive electric fields ( S max / E max ) are calculated as 65.5, 75.1, 100.4, and 88.4 pm/V for films with x = 0, 0.005, 0.01, and 0.015, respectively. The S max / E max value for BNT–BT–0.01BMO thin films is much higher than that of Mn‐doped BNT–BKT thin films (67 pm/V), which is comparable to those of Mn‐doped BNT–BT thin films (92 pm/V) and of BNT–BKT–BMO thin films (116 pm/V) . However, the value is still much lower than the

d_{33}^{*}

value of BiMnO 3 ‐doped BNT‐based ceramics due to the smaller particle sizes of the films and the dead layers at the interface between the films and the substrates, and thin films are still expected to have a tremendous leap in their piezoelectric properties in the future.…”

Section: Resultsmentioning

confidence: 81%

Reduced leakage current and enhanced piezoelectricity of BNT–BT–BMO thin films

Song

et al. 2019

J Am Ceram Soc

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BiMeO3 (where Me denotes a transition metal) is often used as a chemical modifier to form the Bi0.5Na0.5TiO3‐based solid solutions and to improve the electromechanical properties of the materials. In this study, BiMnO3 was selected as a chemical modifier, and (1 − x)(0.94Bi0.5Na0.5TiO3‐0.06BaTiO3)–xBiMnO3 thin films with x = 0, 0.005, 0.01, and 0.015 were fabricated using the metal organic decomposition method to study the contributions of the third end‐member BiMnO3 to the reduction in the leakage current and the enhancement of the piezoelectric properties of Bi0.5Na0.5TiO3‐BaTiO3 thin films. Thin films with 1 mol% BiMnO3 exhibit a lower leakage current, and a better piezoelectricity and ferroelectricity, whose Smax/Emax, Pmax, 2Ec, and εr are 100.4 pm/V, 48.0 μC/cm2, 54.9 kV/cm, and 942, respectively.

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d_{33}^{*}

Section: Resultsmentioning

confidence: 81%

Reduced leakage current and enhanced piezoelectricity of BNT–BT–BMO thin films

Song

et al. 2019

J Am Ceram Soc

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“…In a previous report, the magnetic field and pressure can slightly change the ferroelectric hysteresis loop, and the relative change of the saturated ferroelectric polarization and the remanent ferroelectric polarization were less than 20% at room temperature. 43,44 Therefore, the great change of the saturated ferroelectric polarization and the remanent ferroelectric polarization induced by white light in the BiFeO 3 nanosheets at room temperature is remarkable, which demonstrates potential application for nonvolatile multistate memory devices. Although the light-induced ferroelectricity change has already been observed in ferroelectric compounds, 45,46 where the ferroelectric polarization was suppressed by light, it has never been seen in (anti/ferro/ferri) magnetic compounds nor in magnetoelectric ones.…”

Section: Resultsmentioning

confidence: 99%

White-Light-Controlled Magnetic and Ferroelectric Properties in Multiferroic BiFeO₃ Square Nanosheets

et al. 2014

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Multiferroic materials exhibiting magnetism and ferroelectricity are promising multifunctional materials, especially for spin electronic applications. The magnetoelectric effect was observed in many multiferroic materials, which couples magnetism and ferroelecticity. However, until now, the coupling of light with magnetism and ferroelectricity in multiferroic materials has not been reported yet. Herein we report on the observation of the remarkable white-light-controlled ferromagnetism and ferroelectricity in multiferroic BiFeO 3 nanosheets at room temperature (300 K). The relative white-light-induced reduction of the ferromagnetic polarization is about 30%, and the relative white-light-induced change of the ferroelectric polarization is more than 225%. Furthermore, the BiFeO 3 nanosheets show substantial ferromagnetism (0.2 μB/Fe) at room temperature (300 K). Our result presented in this paper opens a new route for multifunctionality where magnetic polarization and ferroelectric polarization can be controlled simultaneously by light and magnetic field and electric field.

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“…As such, a various of lead‐free candidates have been proposed, including BaTiO 3 , [ 2 ] (K,Na)NbO 3 , [ 3 ] and (Bi,Na)TiO 3 . [ 4 ] To achieve piezoelectric performance that rivals that of lead‐based counterparts, various effective modification strategies have been developed, such as doping and texturing. [ 5 ] For example, highly <001> textured (K,Na)NbO 3 ceramic have been shown to exhibit a PZT‐like piezoelectric coefficient d 33 of 416 pC N −1 .…”

Section: Introductionmentioning

confidence: 99%

An Emerging Family of Piezocatalysts: 2D Piezoelectric Materials

Jin

Liu

Zhang

2023

Small

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Piezocatalysis is an emerging technique that holds great promise for the conversion of ubiquitous mechanical energy into electrochemical energy through piezoelectric effect. However, mechanical energies in natural environment (such as wind energy, water flow energy, and noise) are typically tiny, scattered, and featured with low frequency and low power. Therefore, a high response to these tiny mechanical energies is critical to achieving high piezocatalytic performance. In comparison to nanoparticles or 1D piezoelectric materials, 2D piezoelectric materials possess characteristics such as high flexibility, easy deformation, large surface area, and rich active sites, showing more promise in future for practical applications. In this review, state‐of‐the‐art research progresses on 2D piezoelectric materials and their applications in piezocatalysis are provided. First, a detailed description of 2D piezoelectric materials are offered. Then a comprehensive summary of the piezocatalysis technique is presented and examines the piezocatalysis applications of 2D piezoelectric materials in various fields, including environmental remediation, small‐molecule catalysis, and biomedicine. Finally, the main challenges and prospects of 2D piezoelectric materials and their applications in piezocatalysis are discussed. It is expected that this review can fuel the practical application of 2D piezoelectric materials in piezocatalysis.

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Enhanced ferroelectric and piezoelectric response in Mn-doped Bi0.5Na0.5TiO3–BaTiO3 lead-free film by pulsed laser deposition

Cited by 26 publications

References 26 publications

Reduced leakage current and enhanced piezoelectricity of BNT–BT–BMO thin films

Reduced leakage current and enhanced piezoelectricity of BNT–BT–BMO thin films

White-Light-Controlled Magnetic and Ferroelectric Properties in Multiferroic BiFeO₃ Square Nanosheets

An Emerging Family of Piezocatalysts: 2D Piezoelectric Materials

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Enhanced ferroelectric and piezoelectric response in Mn-doped Bi0.5Na0.5TiO3–BaTiO3 lead-free film by pulsed laser deposition

Cited by 26 publications

References 26 publications

Reduced leakage current and enhanced piezoelectricity of BNT–BT–BMO thin films

Reduced leakage current and enhanced piezoelectricity of BNT–BT–BMO thin films

White-Light-Controlled Magnetic and Ferroelectric Properties in Multiferroic BiFeO3 Square Nanosheets

An Emerging Family of Piezocatalysts: 2D Piezoelectric Materials

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Product

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White-Light-Controlled Magnetic and Ferroelectric Properties in Multiferroic BiFeO₃ Square Nanosheets