Enhanced ferroelectric and piezoelectric responses of (Ba0.85Ca0.15)(Zr0.1Ti0.9)O3 ceramics by Tm3+ amphoteric substitution

Li, Qingting; Zhang, Qianwei; Cai, Wei; Zhou, Chuang; Gao, Rongli; Chen, Gang; Deng, Xiaoling; Wang, Zhenhua; Fu, Chunlin

doi:10.1016/j.matchemphys.2020.123242

Cited by 25 publications

(7 citation statements)

References 57 publications

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“…Adding a BNT precursor prepared by the molten salt method to BCZT was shown to produce an optimal d 33 value of 450 pC N −1 and a k p value of approximately 53% [44]. In another work, Li et al showed that doping BCZT with 0.5% amphoteric Tm 3+ caused the dopant to occupy both A and B sites and increased the piezoelectric coefficient to 523 pC N −1 [45]. Unfortunately, BCZT's low Curie temperature (∼102 • C) is its limiting factor and disqualifies it for applications needing a higher temperature range.…”

Section: Lithium Niobatementioning

confidence: 99%

See 1 more Smart Citation

A review of ceramic, polymer and composite piezoelectric materials

Habib

Lantgios²,

Hornbostel³

2022

J. Phys. D: Appl. Phys.

100

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Piezoelectric materials have been studied for nearly a century now. Initially employed in sonar technology, piezoelectric materials now have a vast set of applications including energy harvesting, sensing and actuation, and have found their way into our everyday lives. Piezoelectric material properties are being further enhanced to improve their performance and be used in novel applications. This review provides an overview of piezoelectric materials, and offers a material science and fabrication perspective on progress towards the development of practical piezoelectric energy harvesters and sensors. Piezoelectric materials have been divided into the three following classes for this review: ceramics, polymers and composites. The prominent materials under each class are examined and compared, with a focus on their linear piezoelectric response in the d33 mode. The three classes of piezoelectric materials are also compared qualitatively for a range of metrics, and the applications that each material class are best suited for is discussed. Novel piezoelectric materials such as ferroelectrets and nanogenerator devices are also reviewed here. It is shown that ceramic piezoelectric materials have strong piezoelectric properties but are stiff and brittle, whereas polymer piezoelectric materials are flexible and lightweight but do not exhibit very good piezoelectric performance. Composite materials are concluded to possess the advantages of both ceramic and polymer materials, with room to tailor-fit properties by modifying the structure and composition.

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Section: Lithium Niobatementioning

confidence: 99%

“…Doping has also been used to improve the Curie temperature. Kumari et al doped BCZT with Bi 3+ and found that it increased T c to 159 • C [45]. In another work, Zhang et al found that doping with 0.1% LiTaO 3 increased the Curie temperature to 129 • C [46].…”

Section: Lithium Niobatementioning

confidence: 99%

A review of ceramic, polymer and composite piezoelectric materials

Habib

Lantgios²,

Hornbostel³

2022

J. Phys. D: Appl. Phys.

100

View full text Add to dashboard Cite

show abstract

“…DPT feature is induced by the enhanced disorder and increased grain size due to the Mg 2+ ions in the BCZT solid solution. 78,79 The decrease in T C is mainly due to the lattice distortion and induced inner stress by the Mg 2+ ions in the BCZT lattice. However, the small concentration of Mg 2+ ions provides excellent temperature stability providing a significant reference for high energy storage density capacitors with remarkable temperature stability over a wide range i.e., −50 °C to 140 °C.…”

Section: Dielectric Propertiesmentioning

confidence: 99%

Review—Modulation of Dielectric, Ferroelectric, and Piezoelectric Properties of Lead-Free BCZT Ceramics by Doping

Verma

Chauhan

Batoo

et al. 2021

ECS J. Solid State Sci. Technol.

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Barium calcium zirconate titanate (BCZT) is one of the most promising lead-free ceramic materials due to its superior electrical properties. BCZT exhibits the existence of morphotropic phase transition (MPB) and polymorphic phase transition (PPT) that are considered as the basis for superior piezoelectric and ferroelectric properties. It also exhibits a high piezoelectric constant (d33 ∼ 620pC/N) and a large remnant polarization (Pr ∼ 17.μC cm −2 ). Due to the presence of a triple point, it also exhibits a high Curie temperature (T C ). These properties make BCZT a fascinating lead-free ceramic material for use in the electrical world. Here, we have studied the effect of doping on the modification of ferroelectric, dielectric, and piezoelectric properties. The modification of electrical properties caused by the change in phase transition temperature, and by structural modification and bulk formation are discussed.

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“…36 The peaks will shift to high-temperature regions as the frequency increases because of the thermally activated relaxation mechanism. 38,39 According to the Arrhenius law, 40 the relaxation time is plotted versus temperature in Fig. 5 inset.…”

Section: Dielectric Propertiesmentioning

confidence: 99%

Effect of Al2O3 Addition on Magnetoelectric Properties of Ni0.5Zn0.5Fe2O4/Ba0.8Sr0.2TiO3 Composite Ceramics

Qin

Zhou

et al. 2021

Journal of Elec Materi

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Magnetoelectric composites have attracted widespread attention during the past few decades due to their strong magnetoelectric coupling effect and potential applications above room temperature. Ni 0.5 Zn 0.5 Fe 2 O 4 /Ba 0.8 Sr 0.2-TiO 3 composites have been prepared by the conventional high-temperature solid-state method and the effects of Al 2 O 3 addition on their microstructure, dielectric, ferroelectric, and magnetic properties studied. x-Ray diffraction (XRD) analysis confirmed the biphase structure of the composites. scanning electron microscopy (SEM) showed that addition of a certain amount of Al 2 O 3 can enhance the density and promote uniform growth of particle size. The sample with 1 wt.% Al 2 O 3 addition exhibited the largest dielectric constant and lowest dielectric loss (< 0.05 at 1 kHz) at high temperature (> 354°C). The sample with 3 wt.% Al 2 O 3 addition presented the best ferroelectric properties, with the highest values of residual polarization (P r = 2.2150 lC/ cm 2 ) and coercive field (E c = 30.6527 kV/cm) among the specimens. The remanent magnetization (M r ) and saturated magnetization (M s ) decreased with increasing Al 2 O 3 content. In short, addition of Al 2 O 3 caused changes in the grain size, density, and defects, and addition of a certain amount of Al 2 O 3 can improve the magnetoelectric properties.

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Enhanced ferroelectric and piezoelectric responses of (Ba0.85Ca0.15)(Zr0.1Ti0.9)O3 ceramics by Tm3+ amphoteric substitution

Cited by 25 publications

References 57 publications

A review of ceramic, polymer and composite piezoelectric materials

A review of ceramic, polymer and composite piezoelectric materials

Review—Modulation of Dielectric, Ferroelectric, and Piezoelectric Properties of Lead-Free BCZT Ceramics by Doping

Effect of Al2O3 Addition on Magnetoelectric Properties of Ni0.5Zn0.5Fe2O4/Ba0.8Sr0.2TiO3 Composite Ceramics

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