Enhanced impedance, electrical conductivity, dielectric properties for colloidal starch-g-poly (methyl methacrylate) supported with semiconductor cadmium sulfide

Abstract

In this study, starch-graft-poly (methyl methacrylate) (starch-g-PMMA) composites doped with different amounts (5, 10, and 15 wt%) of cadmium sulfide (CdS) particles were fabricated for electrical measurements using in-situ polymerization technique. The structural characterization of the samples was studied. The dielectric and conductivity properties of the composites were investigated using impedance analyzer depending on the frequency (100 Hz–20 kHz) at room temperature. Spectroscopy revealed that the dielectric constant (ε′), dielectric loss (ε′′), and real (Z) components of impedance are found to decrease with increasing frequency for both starch-g-PMMA and starch-g-PMMA (5, 10, and 15 wt%) composites. On the contrary, the AC conductivity (σac) of samples increased with increasing frequency. In addition, ε′ and ε′′ values of starch-g-PMMA were lower than composites that added CdS. When the CdS content increased from 0 to 15%, ε′ increased from 5.62 to 15.10 at 100 Hz. AC conductivity was improved after adding the CdS particles. The maximum conductivity value for starch-g-PMMA15%CdS is found to be 3.07 × 10–7 at 100 Hz. When the dielectric properties of composites are evaluated, it is concluded that it is an exciting material for electronic applications in technology.