To enhance the optical
limiting behavior triggered by nonlinear
absorption (NA), wide-band gap MnO
2
nanoparticles were
incorporated into polyvinylpyrrolidone (PVP) polymer nanofibers at
various concentrations. SEM images of the composite nanofibers showed
that MnO
2
nanoparticles are well entrapped in the nanofibers.
With an increase in MnO
2
nanofiller concentration, a widened
optical band gap energy and an increased Urbach energy were observed.
As the concentration of MnO
2
nanofiller in PVP increased,
the NA behavior became more pronounced but weakened with higher input
intensity. This behavior was attributed to the filling of the localized
defect states by one photon absorption (OPA). The NA mechanisms of
the composite nanofibers were examined, considering their band gap
energies and localized defect states. Although all of the composite
nanofibers had OPA, sequential/simultaneous two photon absorption
(TPA), and excited state absorption mechanisms, the higher concentration
of the MnO
2
nanofiller led to stronger NA behavior due
to its more defective structure. The highest optical limiting behavior
was observed for composite nanofibers with the highest concentration
of MnO
2
nanofiller. The results obtained show that these
composite nanofibers with a high linear transmittance and an extended
band gap energy can be used in optoelectronic applications that can
operate in a wide spectral range. Furthermore, their robust NA behavior,
coupled with their promising optical limiting characteristics, positions
them as strong contenders for effective optical limiting applications.