In
the present study the performance of a series of star-like branched
polyacrylamides (SB-PAMs) has been investigated in oil recovery experiments
to ultimately determine their suitability as novel thickening agent
for enhanced oil recovery (EOR) applications. Hereby, SB-PAMs were
compared with conventional linear PAM. The effect of a branched molecular
architecture on rheology, and consequently on oil recovery was discussed.
Rheological measurements identified unique properties for the SB-PAMs,
as those showed higher robustness under shear and higher salt tolerance
than their linear analogues. EOR performance was evaluated by simulating
oil recovery in two-dimensional flow-cell measurements, showing that
SB-PAMs perform approximately 3–5 times better than their linear
analogues with similar molecular weight. The salinity did not influence
the solution viscosity of the SB-PAM, contrarily to what happens for
partially hydrolyzed polyacrylamide (HPAM). Therefore, SB-PAMs are
more resilient under harsh reservoir conditions, which can make them
attractive for EOR applications.