Perovskites are materials with the same crystal structure of calcium titanate (CaTiO 3 ), which were discovered by Gustav Rose in 1839 and named after Russian mineralogist Lev Perovski (1792-1856). [1,2] Perovskites have a general formula of ABX 3 , where A and B are cations with different sizes (A > B) and X is an anion. [3] The crystalline structure of these materials depends on the temperature [4][5][6] and ionic or elemental radii of A, B, and X elements, [7] which could change from a cubic phase to a tetragonal phase or a low-symmetry orthorhombic phase.Perovskites may be separated in two classes: inorganic (such as PbTiO 3 , CaSiO 3 , etc) and hybrid organic-inorganic (CH 3 NH 3 PbI 3 , HCðNH 2 Þ 2 PbI 3 , etc.). Hybrid perovskites are the materials of choice in terms of research regarding photovoltaic applications. In these materials, A is an organic cation (such as methylammonium), and X is a monovalent halide anion (I À , Br À , or Cl À ). [8] The first hybrid perovskite studied was CH 3 NH 3 PbI 3 (MAPI), which was synthesized and described by Weber in 1978. [9] This material was shown to crystallize in three distinct structural phases: cubic above 330 K (space group Pm3m), a tetragonal phase from 160 to 330 K (space group I4/mcm), and an orthorhombic phase below 160 K (space group Pnma). [6,9] Lead halide perovskites have caught the attention of the scientific community in the last decade due to their singular properties, which include a direct bandgap (1.4-3.0 eV), [10][11][12][13] long charge diffusion length (>1 μm), [14] high absorption coefficient, [15] and high defect tolerance. [16] This last characteristic plays a very important role in the electronic properties of the material since it maintains good electronic quality despite the presence of defects. [17,18] So far, their main applications have been in solar cells, [19][20][21][22][23][24][25][26][27][28][29][30][31] light-emitting diodes, [32] lasers, [33] energy conversion and storage applications. [34,35] The first concrete application of hybrid perovskite films as active material in perovskite solar cells (PSCs) was accomplished in 2006 by Kojima et al., [36] who studied MAPbBr 3 PSCs and achieved a power conversion efficiency (PCE) of 2.2%. Some years later, in 2009, they substituted bromide for iodide, and the PCE was increased to 3.8%, even though the devices were unstable. [19] After these seminal works, the efficiency of the devices followed a continuous growth. Promising results came in 2012, when Kim et al. [37] replaced the liquid electrolyte with a hole conductor organic molecule known as spiro-OMeTAD. This change not only improved the stability of the cells but also increased their PCE to 9.7%. This approach was so successful that it remains relevant and in frequent use until now. In 2013, Burschka et al. [23] proposed a sequential (two steps) technique to deposit perovskite films in which firstly a PbI 2 layer is deposited, followed by deposition of methylammonium iodide