Interest in the photocatalytic oxidation of formaldehyde from contaminated wastewater is growing rapidly. The photocatalytic activity of the nanocrystalline Fe 3C /F ¡ co-doped TiO 2 ÀSiO 2 composite film for the degradation of formaldehyde solution under visible light was discussed in this study. The films were characterised by field emission scanning electron microscopy (FE-SEM) equipped with energy-dispersive spectroscopy, X-ray diffraction (XRD), BET surface area, UVÀVis absorption spectroscopy, and photoluminescence spectroscopy. The FE-SEM results revealed that the Fe 3C /F ¡ co-doped TiO 2 ÀSiO 2 film was composed of uniform round-like nanoparticles or aggregates with the size range of 5À10 nm. The XRD results indicated that only the anatase phase was observed in the film. Compared with a pure TiO 2 film and a singly modified TiO 2 film, the Fe 3C /F ¡ co-doped TiO 2 ÀSiO 2 composite film showed the best photocatalytic properties due to its strong visible light adsorption and diminished electrons-holes recombination.