Refractory
organic pollutants pose a great threat to natural ecosystems
and humans due to their potential biotoxicity. This perspective discusses
photoelectrocatalysis (PEC) technology and engineering for the removal
of typical toxic refractory organic pollutants in water systems. Specifically,
PEC is suitable for treating specific types of water with low concentrations
of contaminants and high toxicity. In addition, it can be feasibly
combined with other treatment systems. By analyzing the many advantages
of PEC, the principles and features of PEC systems, including electro-assisted
photocatalysis (EPC) and photoassisted electrocatalysis (PEC) systems,
and their synergistic effects have been systematically clarified.
In accordance, detailed PEC systems, including adsorption-enhanced
PEC, photoelectro-Fenton techniques, selective PEC,and resource recovery,
which can simultaneously remove organic pollutants and transform energy
via PEC, have been further developed and discussed. In this perspective,
the intermediates of PEC oxidation and toxicity studies have also
been highlighted. Finally, challenges and perspectives for the development
of PEC techniques have been proposed for engineering applications.