Enhanced pseudocapacitive performance of two-dimensional Zn-metal organic framework through a post-synthetic amine functionalization

Moradi, Morteza; Mousavi, Mehdi; Pooriraj, Mehdi; Babamoradi, Mohsen; Hajati, Shaaker

doi:10.1016/j.tsf.2022.139187

Cited by 10 publications

(2 citation statements)

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“…The peaks and spikes in the GCD curve are due to a large number of voids present in the MOF while its undergoing an electrochemical reaction; the electrolyte ions start accumulating in the voids, and after reaching a certain potential the accumulated ions undergo oxidation and reduction reactions with the active material as well. The peaks in the GCD curves are in well agreement with the CV results. , The decrease in potential at 0.15 V is due to the sudden drop in the internal resistance of the electrode material. The electrodes keep charging at a higher potential (for times between 300 and 1000 s at a current density of 1 A g –1 ) because of the high leakage current in the higher potential when compared to lower potential.…”

Section: Resultssupporting

confidence: 81%

“…The peaks in the GCD curves are in well agreement with the CV results. 36,37 The decrease in potential at 0.15 V is due to the sudden drop in the internal resistance of the electrode material. The electrodes keep charging at a higher potential (for times between 300 and 1000 s at a current density of 1 A g −1 ) because of the high leakage current in the higher potential when compared to lower potential.…”

Section: Resultsmentioning

confidence: 99%

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Systematic Investigation on the Electrochemical Performance of Pristine Silver Metal–Organic Framework as the Efficient Electrode Material for Supercapacitor Application

et al. 2022

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The pristine silver metal–organic framework (Ag-MOF) is successfully synthesized by the one-pot synthesis method. It serves as the effective electrode material for supercapacitor application because of its excellent conductive frame network and electrochemical activities. The crystal structure, surface morphology, porosity, and chemical configuration of the Ag-MOF are studied and analyzed using X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), high-resolution transmission electron microscopy (HRTEM), Brunauer–Emmett–Teller (BET) theory, and X-ray photoelectron spectroscopy (XPS) analysis. The electrochemical behavior of the electrode material is determined using galvanostatic charge/discharge (GCD), cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS). The aggregated platelike morphology of Ag-MOF provides more electrochemical active sites and shortens the pathway for ion intercalation/deintercalation which results in outstanding electrochemical performance. The maximum specific capacity of 606.2 C g–1 is achieved at a current density of 1 A g–1 in the three-electrode system. The asymmetric supercapacitor device delivers the maximum energy density of 48.69 W h kg–1 at a power density of 608.73 W kg–1. Furthermore, the fabricated device retains an attractive cyclic stability of 131.14% for 5000 cycles at a current density of 5 A g–1 claimed as the novel electrode material in the area of energy storage.

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Section: Resultssupporting

confidence: 81%

Section: Resultsmentioning

confidence: 99%