Dalton Trans.
 2025
DOI: 10.1039/d4dt03150d
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Enhanced reactivity of cationic Au(μ-H)2MCp2 complexes (M = Mo and W) enabled by bulky tris-biaryl phosphines

Martina Landrini,
Miquel Navarro,
Jesús Campos
et al.

Abstract: [(L1)Au(µ-H)2MCp2][BF4] complexes (M = Mo, W) featuring the cavity-shaped tris-2-(4,4’-di-tert-butylbi-phenylyl)phosphine (L1) have been isolated. The tungsten derivative showed a remarkably fast reactivity in photolytic hydride transfer to generate the mononuclear...

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