Enhanced reversibility of red phosphorus/active carbon composite as anode for lithium ion batteries

Wang, Yong-Long; Tian, Li; Yao, Zhiheng; Liu, Feng; Shu, Li; Ye, Shihai

doi:10.1016/j.electacta.2015.02.151

Cited by 81 publications

(46 citation statements)

References 30 publications

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“…[146] It is widely reported that the combination of nanostructuring S materials with mesoporous carbon molecular results in dramatic improvements of both capacity release and stable cycling of electrode for Li-S batteries. [44][45][46]122,148,149] In a typical way, RP is first heated to the sublimation phase, then the sublimate diffuses into the pores by capillary forces and pressure differences, whereupon it can be adsorbed and deposited on the internal surface of porous carbons. Researchers are strongly inclined to obtain carbon encapsulated phosphorus composites through a facile vaporization-condensation method.…”

Section: Vaporization-condensation Strategymentioning

confidence: 99%

“…In 2015, Wang et al, [148] for the first time, fabricated the RP/active carbon composite with a relatively high phosphorus content (60.0 wt%) via this method, showing a good electrochemical performance of LIBs. Persistent efforts have currently been devoted to tackling this problem of low loading phosphorus and modifying this synthetic method to be more effective.…”

Section: Vaporization-condensation Strategymentioning

confidence: 99%

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Advanced Phosphorus‐Based Materials for Lithium/Sodium‐Ion Batteries: Recent Developments and Future Perspectives

Wei

Zhang

et al. 2018

Advanced Energy Materials

173

128

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High‐performance and lost‐cost lithium‐ion and sodium‐ion batteries are highly desirable for a wide range of applications including portable electronic devices, transportation (e.g., electric vehicles, hybrid vehicles, etc.), and renewable energy storage systems. Great research efforts have been devoted to developing alternative anode materials with superior electrochemical properties since the anode materials used are closely related to the capacity and safety characteristics of the batteries. With the theoretical capacity of 2596 mA h g−1, phosphorus is considered to be the highest capacity anode material for sodium‐ion batteries and one of the most attractive anode materials for lithium‐ion batteries. This work provides a comprehensive study on the most recent advancements in the rational design of phosphorus‐based anode materials for both lithium‐ion and sodium‐ion batteries. The currently available approaches to phosphorus‐based composites along with their merits and challenges are summarized and discussed. Furthermore, some present underpinning issues and future prospects for the further development of advanced phosphorus‐based materials for energy storage/conversion systems are discussed.

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Section: Vaporization-condensation Strategymentioning

confidence: 99%

Section: Vaporization-condensation Strategymentioning

confidence: 99%

Advanced Phosphorus‐Based Materials for Lithium/Sodium‐Ion Batteries: Recent Developments and Future Perspectives

Wei

Zhang

et al. 2018

Advanced Energy Materials

173

128

View full text Add to dashboard Cite

show abstract

“…Nanostructuring and nanocomposites have been demonstrated to be effective in alleviating these issues. In particular, nanocomposites of nanosized RP and carbonaceous materials have been reported to able to improve the cell kinetics and suppress the volume-expansion-induced capacity fading [16,[20][21][22][23][24][25][26][27][28][29][30]. Highenergy mechanical ball milling and vaporization-condensation route are the two mostly reported strategies to achieve P/C nanocomposites.…”

Section: Introductionmentioning

confidence: 99%

Hierarchically porous carbon/red phosphorus composite for high-capacity sodium-ion battery anode

Feng

Liu

et al. 2018

Science Bulletin

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“…It is known that in porous carbon, the adsorptivity of the pores is closely related to the pore size [40,41]. The adsorptivity of the micro-pores is much stronger than that of meso-pores.…”

Section: Resultsmentioning

confidence: 99%

Nano-structured red phosphorus/porous carbon as a superior anode for lithium and sodium-ion batteries

Ding

Zhu

et al. 2017

Sci. China Mater.

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To enhance electrochemical performance of lithium or sodium-ion batteries (LIBs or NIBs), active materials are usually filled in porous conductive particles to produce anode composites. However, it is still challenging to achieve high performance anode composites with high specific capacity, excellent rate performance, high initial Coulombic efficiency (ICE) and long cycle life. Based on these requirements, we design and fabricate activated carbon-coated carbon nanotubes (AC@CNT) with hierarchical structures containing micro-and meso-pores. A new structure of phosphorus/carbon composite (P@AC@CNT) is prepared by confining red P in porous carbon through a vaporization-condensation-conversion method. The micro-pores are filled with P, while the meso-pores remain unoccupied, and the pore openings on the particle surface are sealed by P. Due to the unique structure of P@AC@CNT, it displays a high specific capacity of 1674 mA h g −1 at 0.2 C, ultrahigh ICE of 92.2%, excellent rate performance of 1116 mA h g −1 at 6 C, and significantly enhanced cycle stability for LIBs. The application of P@AC@CNT in NIBs is further explored. This method for the fabrication of the special composites with improved electrochemical performance can be extended to other energy storage applications.

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Enhanced reversibility of red phosphorus/active carbon composite as anode for lithium ion batteries

Cited by 81 publications

References 30 publications

Advanced Phosphorus‐Based Materials for Lithium/Sodium‐Ion Batteries: Recent Developments and Future Perspectives

Advanced Phosphorus‐Based Materials for Lithium/Sodium‐Ion Batteries: Recent Developments and Future Perspectives

Hierarchically porous carbon/red phosphorus composite for high-capacity sodium-ion battery anode

Nano-structured red phosphorus/porous carbon as a superior anode for lithium and sodium-ion batteries

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