Enhanced thermal conductivity in epoxy nanocomposites with hybrid boron nitride nanotubes and nanosheets

Su, Junlin; Xiao, Yang; Ren, Mao

doi:10.1002/pssa.201330213

Cited by 44 publications

(39 citation statements)

References 21 publications

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“…These reports and the present work show significantly higher values than reported for BNNTs dispersed into a polymer matrix . The improved breakdown strength and reduced coefficient of thermal expansion, also reported by Zhi et al , illustrates additional multifunctional improvements obtained with electrically insulating, thermally conductive BNNT‐polymer composites.…”

Section: Resultssupporting

confidence: 81%

“…Recent works are addressing this limitation and, with the availability of new commercial BNNTs , there are increased opportunities to study and exploit the properties of BNNTs. The combination of electrical insulation and thermal conductivity is one case where BNNTs offer a clear advantage for application to thermal interface materials and electrically insulating substrates/packaging materials or heat transfer fluids .…”

Section: Introductionmentioning

confidence: 99%

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Thermal conductivity of bulk boron nitride nanotube sheets and their epoxy‐impregnated composites

Jakubinek

Niven

Johnson

et al. 2016

Physica Status Solidi (a)

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Vous avez des questions? Nous pouvons vous aider. Pour communiquer directement avec un auteur, consultez la première page de la revue dans laquelle son article a été publié afin de trouver ses coordonnées. Si vous n'arrivez pas à les repérer, communiquez avec nous à PublicationsArchive-ArchivesPublications@nrc-cnrc.gc.ca. Questions? Contact the NRC Publications Archive team atPublicationsArchive-ArchivesPublications@nrc-cnrc.gc.ca. If you wish to email the authors directly, please see the first page of the publication for their contact information. NRC Publications Archive Archives des publications du CNRCThis publication could be one of several versions: author's original, accepted manuscript or the publisher's version. / La version de cette publication peut être l'une des suivantes : la version prépublication de l'auteur, la version acceptée du manuscrit ou la version de l'éditeur. NRC Publications Record / Notice d'Archives des publications de CNRC:http://nparc.cisti-icist.nrc-cnrc.gc.ca/eng/view/object/?id=01e4ef00-e2d0-4de6-aa56-efc8eba12c43 http://nparc.cisti-icist.nrc-cnrc.gc.ca/fra/voir/objet/?id=01e4ef00-e2d0-4de6-aa56-efc8eba12c43Copyright line will be provided by the publisher pss-Header will be provided by the publisher Review copy -not for distribution (pss-logo will be inserted here by the publisher) The thermal conductivity of bulk, self-supporting boron nitride nanotube (BNNT) sheets composed of nominally 100% BNNTs oriented randomly in-plane was measured by a steady-state, parallel thermal conductance method. The sheets were either collected directly during synthesis or produced by dispersion and filtration. Differences between the effective thermal conductivities of filtrationproduced BNNT buckypaper (~1.5 W m -1 K -1) and lower-density as-synthesized sheets (~0.75 W m -1 K -1 ), which are both porous materials, were primarily due to their density. The measured results indicate similar thermal conductivity, in the range of 7 to 12 W m -1 K -1, for the BNNT network in these sheets. High BNNT-content composites (~30 wt.% BNNTs) produced by epoxy impregnation of the porous BNNT network gave 2 to 3 W m -1 K -1 , more than 10 the baseline epoxy. The combination of manufacturability, thermal conductivity, and electrical insulation offers exciting potential for electrically insulating, thermally conductive coatings and packaging.

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Section: Resultssupporting

confidence: 81%

Section: Introductionmentioning

confidence: 99%

Thermal conductivity of bulk boron nitride nanotube sheets and their epoxy‐impregnated composites

Jakubinek

Niven

Johnson

et al. 2016

Physica Status Solidi (a)

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“…Greater thermally conductive and electrically non‐conductive polymer composite can be produced by combining the effect of 1D and 2D conductive fillers reinforcement, which also shows improved interfacial bonding strength and filler dispersion in polymer matrix. J. Su et al used the synergistic effect of BN nano‐tubes (1D) and BN nano‐sheets (2D) fillers and evaluated enhanced “K” (0.47 W m −1 K −1 ) epoxy composite. S. Wang et al reported the concept of thermal bridging network heat conduction mechanism built by 1D filler materials.…”

Section: Role and Effect Of Filler/hybrid Filler Addition On Thermal mentioning

confidence: 99%

“…Greater thermally conductive and electrically non-conductive polymer composite can be produced by combining the Illustration of heat conduction mechanism in different bridging networking (A) in fibers, (B) in spherical fillers, (C) combination of (A) and (B), and (D) hybrid fillers containing various size and shape of particles (interstitial gap filling) effect of 1D and 2D conductive fillers reinforcement, which also shows improved interfacial bonding strength and filler dispersion in polymer matrix. J. Su et al33 used the synergistic effect of BN nanotubes (1D) and BN nano-sheets (2D) fillers and evaluated enhanced "K" (0.47 W m −1 K −1 ) epoxy composite. S. Wang et al 34 reported the concept of thermal bridging network heat conduction mechanism built by 1D filler materials.…”

mentioning

confidence: 99%

Role, effect, and influences of micro and nano‐fillers on various properties of polymer matrix composites for microelectronics: A review

Balasubramanian

Ramesh²

2018

Polymers for Advanced Techs

153

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Ever since the discovery of polymer composites, its potential has been anticipated for numerous applications in various fields such as microelectronics, automobiles, and industrial applications. In this paper, we review filler reinforced polymer composites for its enormous potential in microelectronic applications. The interface and compatibility between matrix and filler have a significant role in property alteration of a polymer nanocomposites. Ceramic reinforced polymeric nanocomposites are promising candidate dielectric materials for several micro‐ and nano‐electronic devices. Because of its synergistic effect like high thermal conductivity, low thermal expansion, and dielectric constant of ceramic fillers with the polymer matrix, the resultant nanocomposites have high dielectric breakdown strength. The thermal and dielectric properties are discussed in the view of filler alignment techniques and its effect on the composites. Furthermore, the effect of various surface modified filler materials in polymer matrix, concepts of network forming using filler, and benefits of filler alignment are also discussed in this work. As a whole, this review article addresses the overall view to novice researchers on various properties such as thermal and dielectric properties of polymer matrix composites and direction for future research to be carried out.

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“…A novel strategy was designed to enhance thermal conductivity of epoxy composites by filling hybrid 2D boron nitride nanosheets (BNNSs) and 1D boron nitride nanotubes (BNNTs) [98]. The thermal conductivity of epoxy composites with 1-pyrenebutyric acid functionalized BNNTs/BNNSs hybrid fillers was up to 0.47 W/m⋅K at 2 wt% filler loading, higher than that with individual 1-pyrenebutyric acid functionalized BNNTs or BNNSs fillers ( Figure 21).…”

Section: The Synergistic Effect Of 2dmentioning

confidence: 99%

Effect of Filler Shape on the Thermal Conductivity of Thermal Functional Composites

Liu

Chen

Zhou

et al. 2017

Journal of Nanomaterials

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With the rapid development of electronic industry, heat dissipation issue becomes more and more important. Thermal functional composites (TFCs) are usually binary composites, filled with thermal conductive additives (nanomaterials) in matrix, and the composites show good thermal performance. The theoretical and experimental results show that the filler shape is one of the most important but easily overlooked factors. In this article, we provide a systematic review of the effect of the filler shape on the thermal conductivity of TFCs, and the heat transfer enhancement based on synergistic effect is also summed up. Finally, the future trends of further improving thermal properties of TFCs are predicted.

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Enhanced thermal conductivity in epoxy nanocomposites with hybrid boron nitride nanotubes and nanosheets

Cited by 44 publications

References 21 publications

Thermal conductivity of bulk boron nitride nanotube sheets and their epoxy‐impregnated composites

Thermal conductivity of bulk boron nitride nanotube sheets and their epoxy‐impregnated composites

Role, effect, and influences of micro and nano‐fillers on various properties of polymer matrix composites for microelectronics: A review

Effect of Filler Shape on the Thermal Conductivity of Thermal Functional Composites

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