The passivation of interface states remains an important problem for III-V based semiconductor devices. The role of the most stable bound native oxides GaO x ͑0.5Յ x Յ 1.5͒ is of particular interest. Using monochromatic x-ray photoelectron spectroscopy in conjunction with controlled GaAs͑100͒ and InGaAs͑100͒ surfaces, a stable suboxide ͑Ga 2 O͒ bond is detected at the interface but does not appear to be detrimental to device characteristics. In contrast, the removal of the Ga 3+ oxidation state ͑Ga 2 O 3 ͒ is shown to result in the reduction of frequency dispersion in capacitors and greatly improved performance in III-V based devices.