2001
DOI: 10.1103/physrevb.63.094109
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Enhancement of metallic behavior in bismuth cobaltates through lead doping

Abstract: Single crystals of Bi 2 M 3 Co 2 O y phases with M ϭCa, Sr, and Ba were synthesized by the flux method. The undoped Ca and Sr analogs are semiconducting while the Ba analog has a metal to semiconductor transition at Ϸ80 K. Pb-substituted single crystals in which Pb partially substitutes for Bi were prepared by a similar method. Transmission electron microscopy carried out on single crystals of the undoped phases reveals a superstructure similar to that of superconducting bismuth-2212. This superstructure disap… Show more

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Cited by 19 publications
(18 citation statements)
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“…In contrast, temperature dependence of the resistivity measured along the [001] axis (ρ zz ) is rather complicated. As temperature decreases from 340 K, ρ zz first increases, shows a broad maximum at around 200 K, and then decreases below 200 K. The broad peak of the interlayer resistivity indicates incoherent-coherent crossover of electric conduction [15][16][17][18][19][20] at ~200 K. Above ~200 K, transport mean free path along the [001] direction is shorter than the interlayer distance, and the hopping conduction becomes dominant. A similar incoherent-coherent crossover was reported in isostructural SrMnBi 2…”
Section: Resultsmentioning
confidence: 99%
“…In contrast, temperature dependence of the resistivity measured along the [001] axis (ρ zz ) is rather complicated. As temperature decreases from 340 K, ρ zz first increases, shows a broad maximum at around 200 K, and then decreases below 200 K. The broad peak of the interlayer resistivity indicates incoherent-coherent crossover of electric conduction [15][16][17][18][19][20] at ~200 K. Above ~200 K, transport mean free path along the [001] direction is shorter than the interlayer distance, and the hopping conduction becomes dominant. A similar incoherent-coherent crossover was reported in isostructural SrMnBi 2…”
Section: Resultsmentioning
confidence: 99%
“…48 Though superconductivity has not been observed even under high pressure, it seems of great interest to explore other materials with the same type of triangular lattice, including non-Co oxides, and investigate their transport, magnetic, and thermal properties.…”
Section: Discussionmentioning
confidence: 99%
“…Samples, grown as described in ref. [5], were mounted on a liquid He cryostat and cleaved in situ in the ultra-high vacuum chamber with base pressure 2-3×10 -9 Pa. are measured on a sample from the same batch.…”
Section: For Layered Metals Equation (1) Formally Means That Once Thmentioning
confidence: 99%