In this paper, a new approach is proposed to improve the performance of the LNG regasification process in a geothermal-transcritical CO2–LNG cycle by using thermoelectric generators. Energy and exergy analyses were applied to the proposed system and the plant’s performance is compared with the conventional CO2–LNG cycle. To achieve the optimal solution for the system, a multi-objective optimization technique based on a genetic algorithm is used. This study’s findings revealed that in the conventional CO2–LNG cycle, the highest exergy destruction occurs in the preheater. However, integrating a thermoelectric generator allows a portion of this destroyed exergy to be converted into power. The proposed system demonstrated 2% less exergy destruction compared to the conventional system. Moreover, the TEG contributes additional power, increasing the net output power of the system by 24%. This improvement ultimately enhances the overall exergy efficiency of the system. The analysis also concluded that, although a lower LNG mass flow rate reduces the system’s net power output, it improves the exergy efficiency. Overall, the proposed system exhibits an 8.37% higher exergy efficiency and a 24.22% greater net output power compared to the conventional CO2–LNG cycle.