“…1 PbS is a group IV-VI binary element with a low band gap, large exciton Bohr radius (18 nm), extreme quantum connement, high carrier mobility, low thermal conductivity, and other properties, which make strong quantization effects visible even for large particles or crystallites. 3 Hence, it is a promising candidate to play an active role in various optoelectronic devices, such as infrared photodetectors, 4 solar cells, [5][6][7][8] infrared light-emitting diodes (LEDs), 9 thermoelectric cells, 10 near-infrared light-emitting eld-effect transistors, 11 and llers in polymer nanocomposites, 12 and other elds such as telecommunications and biomedical applications. 3 Usually, chemical routes are preferred for the synthesis of nanostructures owing to the simplicity and availability of many controlling key parameters.…”