Enhancing aerobic oxidation of C–H bonds through efficient catalysis of iron MOF–derived Fe3C nanoparticles embedded in porous carbon catalysts

Zhuang, Lei; Jian, Mingyuan; Xue, Ruifang; Li, Nan; Chen, Jie; Fu, Yanghe; Chen, De–Li; Zhu, Weidong; Zhang, Fumin

doi:10.1016/j.apsusc.2023.158883

Cited by 4 publications

(1 citation statement)

References 53 publications

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“…Additionally, a further pair of peaks observed at 709.3 and 720.5 eV are attributed to the 2p 3/2 and 2p 1/2 orbitals of metallic Fe(0) or Fe 3 C species. [45] The high-resolution deconvoluted C1s XPS spectra corresponded to CÀ C (284.3 eV), CÀ O, and CÀ N (288.2 eV) species. [46] Figure 2c shows the high-resolution N1s XPS spectra of FeC-700 catalyst exhibited two representative peaks, arising from graphitic-N (401.3 eV) and pyridinic-N (399.1 eV).…”

Section: Resultsmentioning

confidence: 95%

Fe₃C/Fe Decorated N‐doped Carbon Derived from Tetrabutylammonium tetrachloroferrate Complex as Bifunctional Electrocatalysts for ORR, OER and Zn‐Air Batteries in Alkaline Medium

Ghosh,

Banerjee,

Bhaduri

et al. 2024

Chemistry An Asian Journal

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The emergence of non‐precious metal‐based robust and economic bifunctional oxygen electrocatalysts for both oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) is crucial for the rational design of commercial rechargeable Zn–air batteries (RZAB) with safe energy conversion and storage systems. Herein, a facile strategy to fabricate a cost‐efficient, bifunctional oxygen electrocatalyst Fe3C/Fe decorated N doped carbon (FeC‐700) with a unique structure has been developed by carbonization of a single source precursor, tetrabutylammonium tetrachloroferrate(III) complex. The ORR and OER activity revealed excellent performance (ΔE = 0.77 V) of the FeC‐700 electrocatalyst, comparable to commercial Pt/C and RuO2, respectively. The designed temperature‐tuneable structure provided sufficiently accessible active sites for the continuous passage of electrons by shortening the mass transfer pathway, leading to extremely durable electrocatalysts with high ECSA and amazing charge transfer performance. Remarkably, the assembled Zn–air batteries with the FeC‐700 catalyst as the bifunctional air electrode delivers gratifying charging–discharging ability with an impressive power density of 134 mW cm‐2 with a long lifespan, demonstrating prodigious possibilities for practical application.

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Section: Resultsmentioning

confidence: 95%

Fe₃C/Fe Decorated N‐doped Carbon Derived from Tetrabutylammonium tetrachloroferrate Complex as Bifunctional Electrocatalysts for ORR, OER and Zn‐Air Batteries in Alkaline Medium

Ghosh,

Banerjee,

Bhaduri

et al. 2024

Chemistry An Asian Journal

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Porous Materials for the Heterogeneously Catalyzed Synthesis of High Value‐Added Products: Latest Trends and Future Prospects

Sanoja‐López,

Luque

2024

Chemistry An Asian Journal

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Heterogeneous catalysis currently stands as a foundational area in materials synthesis and applied chemistry. In this context, emphasizing the significance of heterogeneous catalysis in expediting chemical reactions and controlling the formation of desired products using porous materials represents an intriguing approach in the current technological landscape. This work delves into the synthesis and design of a variety of porous materials, encompassing microporous, mesoporous and macroporous materials (e.g. carbonaceous materials, metal oxides, MOFs, zeolites and functionalized analogues), alongside their properties and characteristics pivotal in heterogeneous catalysis. among others, and their subsequent modification, underscoring the significance of tailoring porous materials for specific catalytic applications.

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Synergistic catalytic performance of g-C3N4/UiO-66 based mesoporous carbons: Synthesis, characterization, and applications in oxidation reactions

Mirhosseyni,

Mohammadi Ziarani,

Badiei

2024

Diamond and Related Materials

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Enhancing aerobic oxidation of C–H bonds through efficient catalysis of iron MOF–derived Fe3C nanoparticles embedded in porous carbon catalysts

Cited by 4 publications

References 53 publications

Fe₃C/Fe Decorated N‐doped Carbon Derived from Tetrabutylammonium tetrachloroferrate Complex as Bifunctional Electrocatalysts for ORR, OER and Zn‐Air Batteries in Alkaline Medium

Fe₃C/Fe Decorated N‐doped Carbon Derived from Tetrabutylammonium tetrachloroferrate Complex as Bifunctional Electrocatalysts for ORR, OER and Zn‐Air Batteries in Alkaline Medium

Porous Materials for the Heterogeneously Catalyzed Synthesis of High Value‐Added Products: Latest Trends and Future Prospects

Synergistic catalytic performance of g-C3N4/UiO-66 based mesoporous carbons: Synthesis, characterization, and applications in oxidation reactions

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Enhancing aerobic oxidation of C–H bonds through efficient catalysis of iron MOF–derived Fe3C nanoparticles embedded in porous carbon catalysts

Cited by 4 publications

References 53 publications

Fe3C/Fe Decorated N‐doped Carbon Derived from Tetrabutylammonium tetrachloroferrate Complex as Bifunctional Electrocatalysts for ORR, OER and Zn‐Air Batteries in Alkaline Medium

Fe3C/Fe Decorated N‐doped Carbon Derived from Tetrabutylammonium tetrachloroferrate Complex as Bifunctional Electrocatalysts for ORR, OER and Zn‐Air Batteries in Alkaline Medium

Porous Materials for the Heterogeneously Catalyzed Synthesis of High Value‐Added Products: Latest Trends and Future Prospects

Synergistic catalytic performance of g-C3N4/UiO-66 based mesoporous carbons: Synthesis, characterization, and applications in oxidation reactions

Contact Info

Product

Resources

About

Fe₃C/Fe Decorated N‐doped Carbon Derived from Tetrabutylammonium tetrachloroferrate Complex as Bifunctional Electrocatalysts for ORR, OER and Zn‐Air Batteries in Alkaline Medium

Fe₃C/Fe Decorated N‐doped Carbon Derived from Tetrabutylammonium tetrachloroferrate Complex as Bifunctional Electrocatalysts for ORR, OER and Zn‐Air Batteries in Alkaline Medium