Enhancing enantioselectivity in chiral metal organic framework fluorescent sensors

Thoonen, Shannon; Siripanich, Pattara; Hua, Lisa; Tay, Hui Min; Ramkissoon, Pria; Smith, Trevor A.; Lessio, Martina; Hua, Carol

doi:10.1039/d4qi00760c

Inorg. Chem. Front.

2024

DOI: 10.1039/d4qi00760c

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Enhancing enantioselectivity in chiral metal organic framework fluorescent sensors

Shannon Thoonen,

Pattara Siripanich,

Lisa Hua

et al.

Abstract: The straightforward identification of enantiomers is of large importance to applications in the pharmaceutical, food and agricultural industries. We report the incorporation of two ligands containing the 1,1'-binaphthyl (BINOL) core...

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Chiral 1-D coordination polymer chains featuring 1,1′-binaphthyl

Tay,

Thoonen,

Hua

2024

Aust. J. Chem.

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Four 1-D chain coordination polymers containing bent 1,1′-binaphthyl ligands were synthesised with NiII, CuII and AgI. The use of (R)-4,4′-(2,2′-diethoxy-[1,1′-binaphthalene]-6,6′)dipyridine as a ligand yielded isostructural 1-D looping chains with NiII and CuII, whereas the use of AgI yielded both linear and helical 1-D chains. Changing the dipyridyl coordination groups to dicarboxylates in (S)-6,6′-dicarboxyl-2,2′-diethoxy-1,1′-binaphthalene yielded a 1-D looping chain with a CuII paddlewheel motif. The AgI 1-D chain features two crystallographically distinct 1-D chain morphologies with a triple helix and linear strips. The packing arrangement of the 1-D chains differs because of the intermolecular interactions present, with the steric bulk of the ethoxy substituent on the 1,1′-binaphthyl enabling the formation of large void spaces.

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Chiral 1-D coordination polymer chains featuring 1,1′-binaphthyl

Tay,

Thoonen,

Hua

2024

Aust. J. Chem.

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Enhancing enantioselectivity in chiral metal organic framework fluorescent sensors

Abstract: The straightforward identification of enantiomers is of large importance to applications in the pharmaceutical, food and agricultural industries. We report the incorporation of two ligands containing the 1,1'-binaphthyl (BINOL) core...

Cited by 1 publication

References 46 publications

Chiral 1-D coordination polymer chains featuring 1,1′-binaphthyl

Chiral 1-D coordination polymer chains featuring 1,1′-binaphthyl

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